Ethanedioic acid, ethyl 2-nitrophenyl ester

Base Information

• Chemical Name: Ethanedioic acid, ethyl 2-nitrophenyl ester
• CAS No.: 17318-84-2
• Molecular Formula: C10H9NO6
• Molecular Weight: 239.185
• Mol file: 17318-84-2.mol

Synonyms:

Chemical Property of Ethanedioic acid, ethyl 2-nitrophenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ethanedioic acid, ethyl 2-nitrophenyl ester

There total 2 articles about Ethanedioic acid, ethyl 2-nitrophenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

potassium 2-nitrophenoxide (824-38-4) + Ethyl oxalyl chloride (4755-77-5) → Ethyl o-Nitrophenyl Oxalate (17318-84-2)

Guidance literature:

In toluene; at 20 ℃; for 1h;

DOI:10.1002/prac.19933350409

Reference yield:

→ Ethyl o-Nitrophenyl Oxalate (17318-84-2)

Guidance literature:

Ethyloxalylchlorid, Kalium-o-nitrophenolat;

DOI:10.1021/ja00992a015

Reference yield: 86.0%

Ethyl o-Nitrophenyl Oxalate (17318-84-2) → ethyl (2-hydroxyphenylcarbamoyl)formate (27383-59-1)

Guidance literature:

With methanol; hydrogen; Pt(S)/C; under 760 Torr; Ambient temperature;

DOI:10.1002/prac.19933350409

upstream raw materials:

potassium 2-nitrophenoxide

Ethyl oxalyl chloride

Downstream raw materials:

ethyl (2-hydroxyphenylcarbamoyl)formate

<1,4>-benzoxazine-2,3-dione

Refernces

• 1、 Hartenstein, H.,Sicker, D.. "Syntheses of Cyclic Hydroxamic Acids and Lactams with 2,3-Dioxo-1,4-benzoxazine Skeleton". . p. 359 - 362. Retrieved 2007/10/02.