IrF(CO)[P(C₆H₅)3]2(NHNC₆H₃CF₃)⁽¹⁺⁾*BF₄^(1-)=IrF(CO)[P(C₆H₅)3]2(NHNC₆H₃CF₃)BF₄

Base Information

• Chemical Name: IrF(CO)[P(C₆H₅)3]2(NHNC₆H₃CF₃)⁽¹⁺⁾*BF₄^(1-)=IrF(CO)[P(C₆H₅)3]2(NHNC₆H₃CF₃)BF₄
• CAS No.: 63731-67-9
• Molecular Formula: BF₄*C₄₄H₃₄F₄IrN₂OP₂
• Molecular Weight: 1023.73
• Mol file: 63731-67-9.mol

Synonyms:

Chemical Property of IrF(CO)[P(C₆H₅)3]2(NHNC₆H₃CF₃)⁽¹⁺⁾*BF₄^(1-)=IrF(CO)[P(C₆H₅)3]2(NHNC₆H₃CF₃)BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrF(CO)[P(C₆H₅)3]2(NHNC₆H₃CF₃)⁽¹⁺⁾*BF₄^(1-)=IrF(CO)[P(C₆H₅)3]2(NHNC₆H₃CF₃)BF₄

There total 2 articles about IrF(CO)[P(C₆H₅)3]2(NHNC₆H₃CF₃)⁽¹⁺⁾*BF₄^(1-)=IrF(CO)[P(C₆H₅)3]2(NHNC₆H₃CF₃)BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbonylhydridotris(triphenylphosphine)iridium(I) (33541-67-2) + o-(trifluoromethyl)benzenediazonium tetrafluoroborate → IrF(CO)[P(C6H5)3]2(NHNC6H3CF3)(1+)*BF4(1-)=IrF(CO)[P(C6H5)3]2(NHNC6H3CF3)BF4 (63731-67-9)

Guidance literature:

In acetone; toluene; at 25°C under N2 simultaneous addition of educts 0.1 h, then stirring 0.2 h; evapn., treatment with aq. HBF4 in MeOH/ether/hexane, washing with ether;

DOI:10.1016/S0022-328X(00)98634-0

Reference yield:

HIr(PPh3)2(CO)2 (17250-59-8) + o-(trifluoromethyl)benzenediazonium tetrafluoroborate → IrF(CO)[P(C6H5)3]2(NHNC6H3CF3)(1+)*BF4(1-)=IrF(CO)[P(C6H5)3]2(NHNC6H3CF3)BF4 (63731-67-9) + IrH2(CO)2[P(C6H5)3]2(1+)*BF4(1-)=IrH2(CO)2[P(C6H5)3]2BF4 (83111-59-5)

Guidance literature:

In acetone; toluene; at 25°C under N2 simultaneous addition of educts 0.1 h, then stirring 0.2 h; recovery with MeOH/ether, elem. anal.;

DOI:10.1016/S0022-328X(00)98634-0

upstream raw materials:

carbonylhydridotris(triphenylphosphine)iridium(I)

HIr(PPh₃)2(CO)2