83111-59-5Relevant academic research and scientific papers
ARYLDIAZENIDO, ARYLDIAZENE, AND ARYLHYDRAZIDO COMPLEXES. FURTHER STUDIES OF ortho-METALATED IRIDIUM COMPLEXES DERIVED FROM REACTIONS OF ARYLDIAZONIUM IONS WITH IrH(CO)(PPh3)3 AND IrH(CO)2(PPh3)2
Carroll, James A.,Sutton, Derek,Xiaoheng, Zhang
, p. 73 - 86 (2007/10/02)
The syntheses are described of ortho-metalated iridium arylhydrazido complexes BF4, where X=H, 4-F, 3-F, 2-F, 4-OMe, 2-OMe, 2-NO2, 3-NO2, 3-CH3, 4-CH3 and 2-CF3 from the reactions of the corresponding arenediazonium tetrafluorobo
THE REACTION OF TRIHYDROBISTRIPHENYLPHOSPHINE IRIDIUM IrH3(PPh3)2 WITH DIAZONIUM SALTS
Angoletta, Maria,Caglio, Giorgio
, p. 99 - 106 (2007/10/02)
The reaction of IrH3(PPh3)2 with p-substituted aryldiazonium salts gives the compounds +BF4- at low temperature (-10 deg C) and the o-metalated complexes (R=F, OCH3) at 40-50 deg C.The reactions of the o-metalated complexes with CO, PPh3, NaI and HCl have been studied.
