Manganese, decacarbonyl-m-1,4-phenylenedi-

Base Information

• Chemical Name: Manganese, decacarbonyl-m-1,4-phenylenedi-
• CAS No.: 17477-07-5
• Molecular Formula: C16H4Mn2O10
• Molecular Weight: 466.078
• Mol file: 17477-07-5.mol

Synonyms:

Chemical Property of Manganese, decacarbonyl-m-1,4-phenylenedi-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Manganese, decacarbonyl-m-1,4-phenylenedi-

There total 1 articles about Manganese, decacarbonyl-m-1,4-phenylenedi- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

1,4-C6H4(COMn(CO)5)2 (17477-08-6) → 1,4-C6H3(Mn(CO)5)2 (17477-07-5)

Guidance literature:

In toluene; (N2), refluxed in toluene;

DOI:10.1016/S0277-5387(00)83759-6

Reference yield: 84.0%

1,4-C6H3(Mn(CO)5)2 (17477-07-5) → 1,4-C6H4(COMn(CO)5)2 (17477-08-6)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; (N2), in an autoclave, stirred at room temp. for 22 h; solvent removed (reduced pressure), washed with ether;

DOI:10.1016/S0277-5387(00)83759-6

Reference yield: 71.0%

1,4-C6H3(Mn(CO)5)2 (17477-07-5) → dimanganese decacarbonyl (10170-69-1) + p-xylylene glycol (589-29-7)

Guidance literature:

With carbon monoxide; hydrogen; In tetrahydrofuran; (N2), CO/H2 (1:1), in an autoclave, mixture heated at 70°C for 3.5 h, cooled, gases vented; filtered, solvent removed (reduced pressure), hexane added, filtered, solvent removed, IR, NMR, mass spectra;

DOI:10.1016/S0277-5387(00)83759-6

upstream raw materials:

1,4-C₆H₄(COMn(CO)5)2

Downstream raw materials:

iodo(pentacarbonyl)manganese(I)

para-diiodobenzene

1,4-Mn(CO)5(C₆H₄I)

bromopentacarbonylmanganese(I)