Benzenamine, 4,4'-[1,4-phenylenebis(thio)]bis-

Base Information

Chemical Name:Benzenamine, 4,4'-[1,4-phenylenebis(thio)]bis-
CAS No.:17619-11-3
Molecular Formula:C18H16N2S2
Molecular Weight:324.47
Hs Code.:
DSSTox Substance ID:DTXSID90487265
Nikkaji Number:J2.443.298J
Wikidata:Q82329226

Synonyms:17619-11-3;Benzenamine, 4,4'-[1,4-phenylenebis(thio)]bis-;4,4'-(1,4-Phenylenebis(sulfanediyl))dianiline;4-[4-(4-aminophenyl)sulfanylphenyl]sulfanylaniline;4-({4-[(4-AMINOPHENYL)SULFANYL]PHENYL}SULFANYL)ANILINE;SCHEMBL1098379;DTXSID90487265;MFCD00409012;1,4-bis(4'-aminophenylthio)-benzene;AKOS030581400;AS-67165;CS-0069232;D73800

Suppliers and Price of Benzenamine, 4,4'-[1,4-phenylenebis(thio)]bis-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Benzenamine, 4,4'-[1,4-phenylenebis(thio)]bis-

Chemical Property:

XLogP3:4.2
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:324.07549087
Heavy Atom Count:22
Complexity:283

Purity/Quality:: 99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC(=CC=C1N)SC2=CC=C(C=C2)SC3=CC=C(C=C3)N

Technology Process of Benzenamine, 4,4'-[1,4-phenylenebis(thio)]bis-

There total 5 articles about Benzenamine, 4,4'-[1,4-phenylenebis(thio)]bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 54952-19-1
1,4-bis(4-nitrophenylsulfenyl)benzene

: 17619-11-3
1,4-bis(4'-aminophenylthio)benzene

Guidance literature:: With nickel; hydrazine hydrate; In 1,4-dioxane; water; at 85 ℃;
DOI:10.1007/BF00960284

Reference yield: 84.0%

: 624-38-4,1032416-46-8
para-diiodobenzene

: 1193-02-8
4-aminotiophenol

: 17619-11-3
1,4-bis(4'-aminophenylthio)benzene

Guidance literature:: With copper dichloride; N,N`-dimethylethylenediamine; at 110 ℃; for 24h; Inert atmosphere; Green chemistry;
DOI:10.1055/a-1561-5508

Reference yield:

: 101-59-7
4-amino-4'-nitrodiphenyl sulfide

: 17619-11-3
1,4-bis(4'-aminophenylthio)benzene

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) aq. NaNO₂, 7percent HCl, 2.) aq. KI / 1.) 0 deg C, 1 h, 2.) 60 deg C, 2 h

2: 2.) copper / 1.) methanol, reflux, 15 min, 2.) DMF, 140 deg C, 2 h

3: 87 percent / aq. hydrazine hydrate, Raney Ni / dioxane; H₂O / 85 °C

With hydrogenchloride; nickel; copper; hydrazine hydrate; potassium iodide; sodium nitrite; In 1,4-dioxane; water;
DOI:10.1007/BF00960284