[(N-protonated [2.1.1]-(2,6)-pyridinophane)Pt(II)Me₂]B(C₆H₃(CF₃)2)4]

Base Information

• Chemical Name: [(N-protonated [2.1.1]-(2,6)-pyridinophane)Pt(II)Me₂]B(C₆H₃(CF₃)2)4]
• CAS No.: 717139-16-7
• Molecular Formula: C₂₁H₂₃N₃Pt*C₃₂H₁₂BF₂₄*H
• Molecular Weight: 1376.74
• Mol file: 717139-16-7.mol

Synonyms:

Chemical Property of [(N-protonated [2.1.1]-(2,6)-pyridinophane)Pt(II)Me₂]B(C₆H₃(CF₃)2)4]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(N-protonated [2.1.1]-(2,6)-pyridinophane)Pt(II)Me₂]B(C₆H₃(CF₃)2)4]

There total 1 articles about [(N-protonated [2.1.1]-(2,6)-pyridinophane)Pt(II)Me₂]B(C₆H₃(CF₃)2)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

([2.1.1]-(2,6)-pyridinophane)Pt(II)Me2 (501943-24-4) + trifluorormethanesulfonic acid (1493-13-6) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [(N-protonated [2.1.1]-(2,6)-pyridinophane)Pt(II)Me2]B(C6H3(CF3)2)4] (717139-16-7) + [sym-([2.1.1]-(2,6)-pyridinophane)Pt(IV)Me2H]B(C6H3(CF3)2)4] (547695-25-0,717139-15-6) + [unsym-([2.1.1]-(2,6)-pyridinophane)Pt(IV)Me2H]B(C6H3(CF3)2)4]

Guidance literature:

In dichloromethane-d2; byproducts: NaOSO2CF3; under Ar; mixt. of B compd., Pt complex and CD2Cl2 cooled to -95°C (acetone bath); soln. of HSO3CF3 in CD2Cl2 added dropwise under stirring; stirred at -95°C for 5 min; not isolated; monitored by (1)H NMR spectra; mixt. of three Pt complexeswith protonated ligand, symmetrical and unsymmetrical (8:4:88) obtained at -80°C;

DOI:10.1021/ic034731m

Reference yield:

[(N-protonated [2.1.1]-(2,6)-pyridinophane)Pt(II)Me2]B(C6H3(CF3)2)4] (717139-16-7) + [unsym-([2.1.1]-(2,6)-pyridinophane)Pt(IV)Me2H]B(C6H3(CF3)2)4] → [sym-([2.1.1]-(2,6)-pyridinophane)Pt(IV)Me2H]B(C6H3(CF3)2)4] (547695-25-0,717139-15-6)

Guidance literature:

In dichloromethane-d2; under Ar; in NMR tube; soln. of Pt complexes in CD2Cl2 heated to -45°C; not isolated; monitored by (1)H NMR spectroscopy;

DOI:10.1021/ic034731m

upstream raw materials:

([2.1.1]-(2,6)-pyridinophane)Pt(II)Me₂

trifluorormethanesulfonic acid

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

Downstream raw materials:

[sym-([2.1.1]-(2,6)-pyridinophane)Pt(IV)Me₂H]B(C₆H₃(CF₃)2)4]