Cyclopropyltributylstannane

Base Information

• Chemical Name: Cyclopropyltributylstannane
• CAS No.: 17857-70-4
• Molecular Formula: C15H32Sn
• Molecular Weight: 331.129
• European Community (EC) Number: 868-294-0
• DSSTox Substance ID: DTXSID70449402
• Mol file: 17857-70-4.mol

Synonyms:Cyclopropyltributylstannane;17857-70-4;tributyl(cyclopropyl)stannane;Stannane, tributylcyclopropyl-;MFCD10699177;Tributyl-cyclopropyl-stannane;cyclopropyltributyltin;tributylcyclopropyltin;tributylcyclopropylstannane;tri-n-butyl-cyclopropyltin;tributyl-cyclopropylstannane;tri-n-butyl(cyclopropyl) tin;DTXSID70449402;RUCOUXAHBYBPHL-UHFFFAOYSA-N;AKOS015840809;Cyclopropyltributylstannane, AldrichCPR;GS-6497;SY038161;FT-0685473;H10244;EN300-7377598;J-520197

Chemical Property of Cyclopropyltributylstannane

Chemical Property:

• Vapor Pressure: 0.001mmHg at 25°C
• Boiling Point: 317.958oC at 760 mmHg
• Flash Point: 150.118oC
• PSA: 0.00000
• LogP: 5.99950
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 332.152604
• Heavy Atom Count: 16
• Complexity: 151

Purity/Quality:

97% ^*data from raw suppliers

Cyclopropyltributylstannane 95% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 21-25-36/38-48/23/25-50/53
• Safety Statements: 36/37/39-45-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CCCC)C1CC1

Technology Process of Cyclopropyltributylstannane

There total 3 articles about Cyclopropyltributylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tributyltin chloride (1461-22-9) + cyclopropylmagnesium bromide (23719-80-4) → tri-n-butyl-cyclopropyltin (17857-70-4)

Guidance literature:

In tetrahydrofuran; refluxing;;

Reference yield:

cyclopropyl bromide (4333-56-6,130561-87-4) + tributyltin chloride (1461-22-9) → tri-n-butyl-cyclopropyltin (17857-70-4)

Guidance literature:

cyclopropyl bromide; With iodine; magnesium; In tetrahydrofuran; at 40 - 70 ℃; for 1.75h;

tributyltin chloride; In tetrahydrofuran; at 20 ℃; for 16.5h; Heating / reflux;

With potassium fluoride; water; ammonium chloride; In tetrahydrofuran; at 10 ℃;

Reference yield:

→ tri-n-butyl-cyclopropyltin (17857-70-4)

Guidance literature:

upstream raw materials:

tributyltin chloride

cyclopropylmagnesium bromide

cyclopropyl bromide

Downstream raw materials:

uracil

5-cyclopropyl-pyrimidin-2,4-(1H,3H)-dione

5-cyclopropyl-2,4-bis(trimethylsilyloxy)pyrimidine

O,O'-bis-(trimethylsilyl)uracil