Magnesium Cyclopropane Bromide

Base Information

Chemical Name:Magnesium Cyclopropane Bromide
CAS No.:23719-80-4
Molecular Formula:C3H5BrMg
Molecular Weight:145.282
Hs Code.:29319090
DSSTox Substance ID:DTXSID20455679
Mol file:23719-80-4.mol

Synonyms:Magnesium Cyclopropane Bromide;DTXSID20455679;A816864;J-015192

Suppliers and Price of Magnesium Cyclopropane Bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
CyclopropylmagnesiumBromide(0.5MsolutioninTHF)
25ml
$ 200.00

TCI Chemical
Cyclopropylmagnesium Bromide (ca. 10% in Tetrahydrofuran, ca. 0.7mol/L)
100g
$ 219.00

Sigma-Aldrich
Cyclopropylmagnesium bromide solution 1.0 M in 2-methyltetrahydrofuran
25ml
$ 113.00

Sigma-Aldrich
Cyclopropylmagnesium bromide solution 0.5 M in THF
100ml
$ 267.00

Sigma-Aldrich
Cyclopropylmagnesium bromide solution 1.0 M in 2-methyltetrahydrofuran
100ml
$ 278.00

Sigma-Aldrich
Cyclopropylmagnesium bromide solution 0.5 M in THF
800ml
$ 1610.00

Matrix Scientific
Cyclopropylmagnesium bromide 1.0 M in THF97%
500ml
$ 892.00

Matrix Scientific
Cyclopropylmagnesium bromide 1.0 M in THF97%
100ml
$ 468.00

Matrix Scientific
Cyclopropylmagnesium bromide 1.0 M in THF97%
50ml
$ 343.00

American Custom Chemicals Corporation
CYCLOPROPYLMAGNESIUM BROMIDE 95.00%
100G
$ 2693.16

Total 64 raw suppliers

Chemical Property of Magnesium Cyclopropane Bromide

Chemical Property:

Appearance/Colour:clear colorless solution
Vapor Pressure:5350mmHg at 25°C
Boiling Point:65 °C
Flash Point:65°C
PSA：0.00000
Density:0.968 g/mL at 25 °C
LogP:1.96360
Storage Temp.:2-8°C
Sensitive.:Air & Moisture Sensitive
Water Solubility.:Soluble in water (17 mg/ml), (25°C). Soluble in organic solvents.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:143.94250
Heavy Atom Count:5
Complexity:7.5

Purity/Quality:

97% ^*data from raw suppliers

CyclopropylmagnesiumBromide(0.5MsolutioninTHF) ^*data from reagent suppliers

Safty Information:

Pictogram(s): F, Xi
Hazard Codes:F,Xi,C
Statements: 11-14-19-36/37/38-40-37-34
Safety Statements: 16-26-45-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C[CH-]1.[Mg+2].[Br-]
Uses It often acts as the starting nutrient mix for dropout studies where fermentation conditions required the absence of one or more essential amino acids. For classifying Yeasts based on colonial characteristics and cell morphology. Cyclopropylmagnesium bromide solution has been used in Grignard reaction that finds application as the key step in the preparation of aminopropylindenes, a chemotype of oxidosqualene cyclase (OSC) inhibitors from Grundmann′s ketone. It can react with trimethylborate to form cyclopropylboronic acid, which can undergo Suzuki-type coupling reactions with different aryl, and heteroaryl bromides to form the cyclopropyl adducts.

Technology Process of Magnesium Cyclopropane Bromide

There total 3 articles about Magnesium Cyclopropane Bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4333-56-6,130561-87-4
cyclopropyl bromide

: 23719-80-4
cyclopropylmagnesium bromide

: 75-19-4
cyclopropane

Guidance literature:: With magnesium; In diethyl ether; at 36 - 40 ℃; Product distribution; Mechanism; other solvents, also deuterated dicyclohexylphosphine (DCPD) as reagent;
DOI:10.1021/ja00039a007