Phosphine sulfide, [3-(diphenylphosphino)propyl]diphenyl-

Base Information

• Chemical Name: Phosphine sulfide, [3-(diphenylphosphino)propyl]diphenyl-
• CAS No.: 178820-90-1
• Molecular Formula: C₂₇H₂₆P₂S
• Molecular Weight: 444.517
• Mol file: 178820-90-1.mol

Synonyms:

Chemical Property of Phosphine sulfide, [3-(diphenylphosphino)propyl]diphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphine sulfide, [3-(diphenylphosphino)propyl]diphenyl-

There total 2 articles about Phosphine sulfide, [3-(diphenylphosphino)propyl]diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diphenylphosphane sulfide (6591-07-7) → Ph2P(CH2)3P(S)Ph2 (178820-90-1)

Guidance literature:

Reference yield:

lithium diphenylphosphide (65567-06-8,4541-02-0) + (3-chloropropyl)diphenylphosphine sulfide (177531-35-0) → Ph2P(CH2)3P(S)Ph2 (178820-90-1)

Guidance literature:

Reference yield: 97.0%

cis-[ruthenium(II)(CO)2Cl2-η1(P)-(Ph2P(CH2)3P(S)Ph2)] (628688-04-0) + Ph2P(CH2)3P(S)Ph2 (178820-90-1) → cis-[ruthenium(II)(CO)2Cl2-η1(P)-(Ph2P(CH2)3P(S)Ph2)2] (628688-08-4)

Guidance literature:

In dichloromethane; soln. of Ph2P(CH2)3P(S)Ph2 in CH2Cl2 added to soln. of Ru complex in CH2Cl2, mixt. stirred at room temp. for about 2 h; evapd., residue washed with diethyl ether, recrystd. from CH2Cl2; elem. anal.;

DOI:10.1016/S0277-5387(03)00371-1

upstream raw materials:

lithium diphenylphosphide

(3-chloropropyl)diphenylphosphine sulfide

diphenylphosphane sulfide

Downstream raw materials:

cis-[ruthenium(II)(CO)2Cl2-η1(P)-(Ph2P(CH2)3P(S)Ph2)2]

[Ag(SP(C₆H₅)2(CH₂)3P(C₆H₅)2)NO₃]2

cis-[ruthenium(II)(CO)2Cl2-η1(P)-(Ph2P(CH2)3P(S)Ph2)]

cis-[Ru(CO)2I2(η1-P-Ph2P(CH2)3P(S)Ph2)]

Refernces