carbonyl(η5-cyclopentadienyl)[methoxy(methyl)carbene](triphenylphosphine)iron(II) fluorosulfonate

Base Information

Chemical Name:carbonyl(η5-cyclopentadienyl)[methoxy(methyl)carbene](triphenylphosphine)iron(II) fluorosulfonate
CAS No.:49547-60-6
Molecular Formula:C₂₇H₂₆FeO₂P*FO₃S
Molecular Weight:568.386
Hs Code.:

Synonyms:

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Chemical Property of carbonyl(η5-cyclopentadienyl)[methoxy(methyl)carbene](triphenylphosphine)iron(II) fluorosulfonate

Chemical Property:

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Technology Process of carbonyl(η5-cyclopentadienyl)[methoxy(methyl)carbene](triphenylphosphine)iron(II) fluorosulfonate

There total 2 articles about carbonyl(η5-cyclopentadienyl)[methoxy(methyl)carbene](triphenylphosphine)iron(II) fluorosulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 421-20-5
Methyl fluorosulfonate

: acetyl carbonyl cyclopentadienyl triphenylphosphine iron

: 49547-60-6
carbonyl(η5-cyclopentadienyl)[methoxy(methyl)carbene](triphenylphosphine)iron(II) fluorosulfonate

Guidance literature:: In benzene; to Fe complex in benzene added dropwise MeOSO2F in benzene, stirred for3 h; ppt. sepd., washed with benzene, dried in vac.; elem. anal.;
DOI:10.1016/0022-328X(83)80206-X

Reference yield:

: 421-20-5
Methyl fluorosulfonate

: 41560-73-0
carbonyl(η5-cyclopentadienyl)[η1-1-(methoxy)vinyl](triphenylphosphine)iron(II)

: 86166-69-0
[(C₅H₅)(CO)((C₆H₅)3P)FeC(OCH₃)CH(CH₃)2]⁽¹⁺⁾*SO₃F^(1-)=[(C₅H₅)(CO)((C₆H₅)3P)FeC(OCH₃)CH(CH₃)2]SO₃F

: 86142-99-6
[(C₅H₅)(CO)((C₆H₅)3P)FeC(OCH₃)C₂H₅]⁽¹⁺⁾*SO₃F^(1-)=[(C₅H₅)(CO)((C₆H₅)3P)FeC(OCH₃)C₂H₅]SO₃F

: 49547-60-6
carbonyl(η5-cyclopentadienyl)[methoxy(methyl)carbene](triphenylphosphine)iron(II) fluorosulfonate

Guidance literature:: In benzene; benzene soln. of MeOSO2F added dropwise over 15 min to benzene soln. ofFe complex, stirred for 24 h; ppt. sepd., washed with benzene, dried in vac.; NMR anal.;

Reference yield:

: 14580-91-7,29218-61-9
trimethyl(methylene)phosphorane

: 49547-60-6
carbonyl(η5-cyclopentadienyl)[methoxy(methyl)carbene](triphenylphosphine)iron(II) fluorosulfonate

: 41560-73-0
carbonyl(η5-cyclopentadienyl)[η1-1-(methoxy)vinyl](triphenylphosphine)iron(II)

: (CH₃)4P⁽¹⁺⁾*SO₃F^(1-)=[(CH₃)4P]SO₃F

Guidance literature:: In pentane; to suspn. of Fe complex in pentane added dropwise at -40°C soln.of Me3PCH2 in pentane, warmed to room temp. within 3 h with stirring; filtered, evapd. in vac., taken up in pentane, crystd. at -78°C;elem. anal.;
DOI:10.1016/0022-328X(83)80206-X