tetraphenylarsonium tetrachloro-oxochromate(V)

Base Information

• Chemical Name: tetraphenylarsonium tetrachloro-oxochromate(V)
• CAS No.: 57298-28-9
• Molecular Formula: C₂₄H₂₀As*Cl₄CrO
• Molecular Weight: 593.152
• Mol file: 57298-28-9.mol

Synonyms:

Chemical Property of tetraphenylarsonium tetrachloro-oxochromate(V)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of tetraphenylarsonium tetrachloro-oxochromate(V)

There total 1 articles about tetraphenylarsonium tetrachloro-oxochromate(V) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chromium(VI) oxide + hydrogenchloride (7647-01-0,15364-23-5) + tetraphenylarsonium chloride (507-28-8,14842-08-1) → tetraphenylarsonium tetrachloro-oxochromate(V) (57298-28-9)

Guidance literature:

In acetic acid; (in a dry box, under N2), mixing of CrO3 soln. (in glacial acetic acid saturated with HCl) with AsPh4Cl in similar soln. (according to K. R. Seddan and V. H. Thomas, J. Chem. Soc. Dalton Trans 1977, 2195); filtration of the powder, washing with glacial acetic acid; vac. drying;recrystn. (CH2Cl2);

DOI:10.1002/zaac.200600219

Reference yield:

tetraphenylarsonium tetrachloro-oxochromate(V) (57298-28-9) + Triphenylphosphine oxide (791-28-6) → CrCl4O(OP(C6H5)3)(1-)

Guidance literature:

In dichloromethane; N2-atmosphere; not isolated, detd. by ESR spectroscopy;

DOI:10.1039/DT9770001726

upstream raw materials:

hydrogenchloride

tetraphenylarsonium chloride