Oxirane, 2-methyl-2,3-diphenyl-, (2R,3R)-

Base Information

Chemical Name:Oxirane, 2-methyl-2,3-diphenyl-, (2R,3R)-
CAS No.:184046-33-1
Molecular Formula:C15H14O
Molecular Weight:210.276
Hs Code.:
DSSTox Substance ID:DTXSID10452596
Nikkaji Number:J947.682B
Wikidata:Q82273327
Mol file:184046-33-1.mol

Synonyms:Oxirane, 2-methyl-2,3-diphenyl-, (2R,3R)-;184046-33-1;SCHEMBL7107611;DTXSID10452596;2-Methyl-2alpha,3beta-diphenyloxirane

Suppliers and Price of Oxirane, 2-methyl-2,3-diphenyl-, (2R,3R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Oxirane, 2-methyl-2,3-diphenyl-, (2R,3R)-

Chemical Property:

XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:210.104465066
Heavy Atom Count:16
Complexity:238

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C(O1)C2=CC=CC=C2)C3=CC=CC=C3
Isomeric SMILES:C[C@]1([C@H](O1)C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Oxirane, 2-methyl-2,3-diphenyl-, (2R,3R)-

There total 9 articles about Oxirane, 2-methyl-2,3-diphenyl-, (2R,3R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 833-81-8
(E)-1,2-diphenylpropene

: 184046-33-1
(R,R)-1-Methyl-1,2-diphenyloxirane

Guidance literature:: With Oxone; Shi's ketone; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; potassium hydroxide; In water; acetonitrile; at 0 ℃; for 3.5h; enantioselective reaction; Cooling with ice;
DOI:10.15227/orgsyn.080.0009

Reference yield: 2.0%

: 833-81-8
(E)-1,2-diphenylpropene

: 184046-33-1
(R,R)-1-Methyl-1,2-diphenyloxirane

: 157605-73-7
(2S,3S)-2-methyl-2,3-diphenyloxirane

: 2042-85-5
1,2-diphenylpropan-1-one

Guidance literature:: With 2,3,5,6-tetramethylpyrazine-N,N'-dioxide; [RuCl(C₆₀H₄₄N₂O₂)(NO)]; In 1,4-dioxane; at 20 ℃; for 17.5h; Title compound not separated from byproducts; Irradiation;
DOI:10.1002/1521-3765(20010903)7:17<3776::AID-CHEM3776>3.0.CO;2-M

Reference yield:

: 833-81-8,1017-22-7,34473-62-6,85165-70-4,779-51-1
1,2-diphenylpropene

: 184046-33-1
(R,R)-1-Methyl-1,2-diphenyloxirane

: 157605-73-7
(2S,3S)-2-methyl-2,3-diphenyloxirane

Guidance literature:: With 4,5-di-O-acetyl-3-hydroxy-1,2-O-isopropylidene-D-fructopyranose; oxone; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; In Dimethoxymethane; water; acetonitrile; at 0 ℃; pH=6 - 9; optical yield given as %ee; enantioselective reaction; aq. buffer;
DOI:10.1055/s-0028-1083545