Benzene, 1-nitro-4-(1-propenyl)-, (E)-

Base Information

• Chemical Name: Benzene, 1-nitro-4-(1-propenyl)-, (E)-
• CAS No.: 1879-55-6
• Molecular Formula: C9H9NO2
• Molecular Weight: 163.176
• Mol file: 1879-55-6.mol

Synonyms:1-Nitro-4-((E)-propenyl)-benzene;(E)-1-nitro-4-(prop-1-en-1-yl)benzene;(E)-1-(4-nitrophenyl)propene;(E)-1-nitro-4-(prop-1-enyl)benzene;

Chemical Property of Benzene, 1-nitro-4-(1-propenyl)-, (E)-

Chemical Property:

• PSA: 45.82000
• LogP: 3.15110

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, 1-nitro-4-(1-propenyl)-, (E)-

There total 24 articles about Benzene, 1-nitro-4-(1-propenyl)-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(E)-propenylboronic acid (6336-44-3,7547-96-8,88982-39-2,7547-97-9) + para-nitrophenyl bromide (586-78-7) → (E)-1-nitro-4-(prop-1-en-1-yl)benzene (1879-55-6)

Guidance literature:

With orotic acid; caesium carbonate; In acetone; at 80 ℃; for 14h; Inert atmosphere;

DOI:10.1055/s-0031-1290885

Reference yield: 87.0%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + para-nitrophenyl bromide (586-78-7) → (E)-1-nitro-4-(prop-1-en-1-yl)benzene (1879-55-6)

Guidance literature:

With palladium diacetate; triethylamine; In 1-methyl-pyrrolidin-2-one; at 110 ℃; for 2h; under 12001.2 Torr;

DOI:10.1016/j.ejmech.2017.06.023

Reference yield: 80.0%

4-chlorobenzonitrile (100-00-5) + (E)-propenyl-tri-n-butylstannane (105494-65-3,66680-85-1,66680-84-0) → (E)-1-nitro-4-(prop-1-en-1-yl)benzene (1879-55-6)

Guidance literature:

With palladium diacetate; orotic acid; cesium fluoride; In 1,4-dioxane; at 100 ℃; for 18h; Sealed tube; Inert atmosphere; Schlenk technique;

DOI:10.3184/174751913X13635315066265

upstream raw materials:

2-methyl-3-(4-nitrophenyl)acrylic acid

1-(1-bromopropyl)-4-nitrobenzene

ethyltriphenylphosphonium bromide

4-nitrobenzaldehdye

Downstream raw materials:

trans-p-nitro-(2'-methylcyclopropyl)benzene

N-Hydroxy-N-[((E)-4-propenyl)-phenyl]-acetamide