4-BROMOPHENYLTRIETHOXYSILANE

Base Information

• Chemical Name: 4-BROMOPHENYLTRIETHOXYSILANE
• CAS No.: 18954-74-0
• Molecular Formula: C12H19BrO3Si
• Molecular Weight: 319.271
• Mol file: 18954-74-0.mol

Synonyms:

Chemical Property of 4-BROMOPHENYLTRIETHOXYSILANE

Chemical Property:

• PSA: 27.69000
• LogP: 2.70450

Purity/Quality:

95%~99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-BROMOPHENYLTRIETHOXYSILANE

There total 7 articles about 4-BROMOPHENYLTRIETHOXYSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

Triethoxysilane (998-30-1) + [Rh(cod)(CH3CN)2] + 1,4-bromoiodobenzene (589-87-7) → (4-bromophenyl)triethoxysilane (18954-74-0)

Guidance literature:

With triethylamine;

Reference yield: 81.0%

Triethoxysilane (998-30-1) + 1,4-bromoiodobenzene (589-87-7) → (4-bromophenyl)triethoxysilane (18954-74-0)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; triethylamine; bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; In N,N-dimethyl-formamide; at 80 ℃; for 1h;

DOI:10.1016/j.tet.2007.08.011

Reference yield: 68.0%

Triethoxysilane (998-30-1) + 1,4-bromoiodobenzene (589-87-7) → bromobenzene (108-86-1,52753-63-6) + (4-bromophenyl)triethoxysilane (18954-74-0)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; johnphos; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 2h;

DOI:10.1021/jo010621q

upstream raw materials:

ethanol

(4-bromophenyl)trichlorosilane

Triethoxysilane

1,4-bromoiodobenzene

Downstream raw materials:

1-(4-bromo-phenyl)-2,9,10-trioxa-6-aza-1-sila-bicyclo[4.3.3]dodecane

1-(4-Bromo-phenyl)-2,8,9-trioxa-5λ⁴-aza-1λ⁵-sila-tricyclo[3.3.3.0^1,5]undecane

5-(4-bromophenyl)silatrane

(4-bromophenyl)(ethoxy)[di(prop-2-enyl)]silane