(7-Methyl-oct-6-enyloxy)-benzene

Base Information

• Chemical Name: (7-Methyl-oct-6-enyloxy)-benzene
• CAS No.: 19100-99-3
• Molecular Formula: C15H22O
• Molecular Weight: 218.339
• DSSTox Substance ID: DTXSID90705310
• Mol file: 19100-99-3.mol

Synonyms:(7-methyl-oct-6-enyloxy)-benzene;19100-99-3;DTXSID90705310;[(7-METHYLOCT-6-EN-1-YL)OXY]BENZENE

Chemical Property of (7-Methyl-oct-6-enyloxy)-benzene

Chemical Property:

• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 218.167065321
• Heavy Atom Count: 16
• Complexity: 186

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CCCCCCOC1=CC=CC=C1)C

Technology Process of (7-Methyl-oct-6-enyloxy)-benzene

There total 4 articles about (7-Methyl-oct-6-enyloxy)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1-bromo-7-methyloct-6-ene (463964-83-2) + phenol (108-95-2,27073-41-2) → 7-Methyl-1-phenoxy-octen-(6) (19100-99-3)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 60 ℃; for 1h; Darkness; Inert atmosphere;

DOI:10.1021/jacs.6b01555

Reference yield:

6-bromohexyloxybenzene (51795-97-2) → 7-Methyl-1-phenoxy-octen-(6) (19100-99-3)

Guidance literature:

Multi-step reaction with 2 steps

1: ethanol / Heating

2: (i) PhLi, THF, (ii) /BRN= 635680/

In ethanol;

DOI:10.1039/j39680001331

Reference yield:

(5-phenoxypentyl)triphenylphosphonium bromide (19100-98-2) + acetone (67-64-1) → 7-Methyl-1-phenoxy-octen-(6) (19100-99-3)

Guidance literature:

Multistep reaction; (i) PhLi, THF, (ii) /BRN= 635680/;

DOI:10.1039/j39680001331

upstream raw materials:

(5-phenoxypentyl)triphenylphosphonium bromide

acetone

6-bromohexyloxybenzene

1-bromo-7-methyloct-6-ene