Silane, (1,1-dimethylethyl)[[(1S)-1-ethynylhexyl]oxy]diphenyl-

Base Information

Chemical Name:Silane, (1,1-dimethylethyl)[[(1S)-1-ethynylhexyl]oxy]diphenyl-
CAS No.:192765-48-3
Molecular Formula:C24H32OSi
Molecular Weight:364.603
Hs Code.:
DSSTox Substance ID:DTXSID60449017
Nikkaji Number:J1.341.486F
Wikidata:Q82268298

Synonyms:Silane, (1,1-dimethylethyl)[[(1S)-1-ethynylhexyl]oxy]diphenyl-;192765-48-3;DTXSID60449017;(S)-3-(tert-Butyldiphenylsilyloxy)-1-octyne

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Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, (1,1-dimethylethyl)[[(1S)-1-ethynylhexyl]oxy]diphenyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:9
Exact Mass:364.222242174
Heavy Atom Count:26
Complexity:425

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCCCCC(C#C)O[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C(C)(C)C
Isomeric SMILES:CCCCC[C@@H](C#C)O[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C(C)(C)C

Technology Process of Silane, (1,1-dimethylethyl)[[(1S)-1-ethynylhexyl]oxy]diphenyl-

There total 6 articles about Silane, (1,1-dimethylethyl)[[(1S)-1-ethynylhexyl]oxy]diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 128899-38-7
(S )-1-(trimethylsilyl)oct -1-yn-3-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 192765-48-3
(3S)-3-(tert-butyl-diphenylsilyloxy)-oct-1-yne

Guidance literature:: (S )-1-(trimethylsilyl)oct -1-yn-3-ol; tert-butylchlorodiphenylsilane; With 1H-imidazole;

With methanol; potassium carbonate;
DOI:10.1055/s-0033-1338961

Reference yield: 71.0%

: tert-Butyl-[(S)-1-(2,2-dibromo-vinyl)-hexyloxy]-diphenyl-silane

: 192765-48-3
(3S)-3-(tert-butyl-diphenylsilyloxy)-oct-1-yne

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; 1) -78 deg C -> -30 deg C, 2) -30 deg C, 1 h;
DOI:10.1016/S0040-4020(97)00475-4

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 192765-48-3
(3S)-3-(tert-butyl-diphenylsilyloxy)-oct-1-yne

Guidance literature:: Multi-step reaction with 5 steps

2: 92 percent / H₂ / Pd-C / ethyl acetate / 12 h / Ambient temperature

3: Dess-Martin periodinane / CH₂Cl₂ / 0.17 h / Ambient temperature

4: 1) Zn, PPh₃ / 1) CH₂Cl₂, 24 h, 2) CH₂Cl₂, 0 deg C, 2 h

5: 71 percent / n-BuLi / tetrahydrofuran; hexane / 1) -78 deg C -> -30 deg C, 2) -30 deg C, 1 h

With n-butyllithium; hydrogen; Dess-Martin periodane; triphenylphosphine; zinc; palladium on activated charcoal; In tetrahydrofuran; hexane; dichloromethane; ethyl acetate;
DOI:10.1016/S0040-4020(97)00475-4