MePhSn(1,3-dithiole-2-thione-4,5-dithiolate)

Base Information

• Chemical Name: MePhSn(1,3-dithiole-2-thione-4,5-dithiolate)
• CAS No.: 179736-46-0
• Molecular Formula: C₁₀H₈S₅Sn
• Molecular Weight: 407.214
• Mol file: 179736-46-0.mol

Synonyms:

Chemical Property of MePhSn(1,3-dithiole-2-thione-4,5-dithiolate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of MePhSn(1,3-dithiole-2-thione-4,5-dithiolate)

There total 1 articles about MePhSn(1,3-dithiole-2-thione-4,5-dithiolate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenyl methyl tin dibromide (21247-36-9) + bis(tetraethylammonium)bis(2-thioxo-1,3-dithiole-4,5-dithiolate)zincate (72022-68-5) → MePhSn(1,3-dithiole-2-thione-4,5-dithiolate) (179736-46-0)

Guidance literature:

In acetone; Sonication; ultrasonication of mixt. of 1 equiv. of Zn-complex and 2 equiv. of Sn-halide for 10 min; shaking with H2O, addn. of petroleum ether (pptn.), collection (filtration), refluxing for 1 h in H2O/MeOH=2:1, filtration, drying (vac.), recrystn. (petroleum ether/Me2CO or petroleum ether/MeOH, not specified); elem. anal.;

DOI:10.1016/0022-328X(96)06139-6

upstream raw materials:

phenyl methyl tin dibromide

bis(tetraethylammonium)bis(2-thioxo-1,3-dithiole-4,5-dithiolate)zincate