tetraphenylphosphonium perchlorate

Base Information

• Chemical Name: tetraphenylphosphonium perchlorate
• CAS No.: 19859-51-9
• Molecular Formula: C24H20P.ClO4
• Molecular Weight: 438.84
• Mol file: 19859-51-9.mol

Synonyms:Tetraphenylphosphonium perchlorate; LogP

Chemical Property of tetraphenylphosphonium perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tetraphenylphosphonium perchlorate

There total 6 articles about tetraphenylphosphonium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

phenyl(2,2-dimethyl-4-(diethylphosphono)-2,5-dihydro-3-furyl)iodonium perchlorate → tetraphenylphosphonium perchlorate (19859-51-9) + 2,2-dimethyl-3-iodo-4-(diethylphosphono)-2,5-dihydrofuran (139731-58-1) + [4-(Diethoxy-phosphoryl)-2,2-dimethyl-2,5-dihydro-furan-3-yl]-triphenyl-phosphonium; perchlorate

Guidance literature:

With triphenylphosphine; In acetonitrile; for 24h; Ambient temperature;

DOI:10.1021/jo00034a043

Reference yield: 20.0%

phenyl(2,2-dimethyl-4-(diethylphosphono)-2,5-dihydro-3-furyl)iodonium perchlorate + triphenylphosphine (603-35-0) → tetraphenylphosphonium perchlorate (19859-51-9) + 2,2-dimethyl-3-iodo-4-(diethylphosphono)-2,5-dihydrofuran (139731-58-1) + [4-(Diethoxy-phosphoryl)-2,2-dimethyl-2,5-dihydro-furan-3-yl]-triphenyl-phosphonium; perchlorate

Guidance literature:

In acetonitrile; for 24h; Ambient temperature;

DOI:10.1021/jo00034a043

Reference yield:

(PPh4)2[W(CN)6(bpy)].4H2O → tetraphenylphosphonium perchlorate (19859-51-9)

Guidance literature:

With perchloric acid; In water; acetonitrile; at 80 ℃;

DOI:10.1016/j.poly.2021.115369

upstream raw materials:

triphenylphosphine

iodosylbenzene

tetraphenyl phosphonium chloride

Refernces

• 1、 Hodorowicz, Maciej,Jurowska, Anna,Szklarzewicz, Janusz. "Structures of alkali metal salts with [W(CN)6(bpy)]? ion. Comparative studies to W(IV) analogues". . . Retrieved 2021/07/28.
• 2、 Zefirov, N. S.,Koz'min, A. S.,Kasumov, T.,Potekhin, K. A.,Sorokin, V. D.,et al.. "Interaction of an Allene with Polyvalent Iodine Derivatives. Preparation, X-ray Molecular Structure, and Some Reactions of Phenyl(2,2-dimethyl-4-(diethylphosphono)-2,5-dihydro-3-furyl)iodonium Salts". . p. 2433 - 2437. Retrieved 2007/10/02.