Stannane, trimethyl(5-phenyl-2-furanyl)-

Base Information

Chemical Name:Stannane, trimethyl(5-phenyl-2-furanyl)-
CAS No.:199469-63-1
Molecular Formula:C13H16OSn
Molecular Weight:306.979
Hs Code.:

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Chemical Property of Stannane, trimethyl(5-phenyl-2-furanyl)-

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Technology Process of Stannane, trimethyl(5-phenyl-2-furanyl)-

There total 2 articles about Stannane, trimethyl(5-phenyl-2-furanyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 17113-33-6
2-phenylfuran

: 1066-45-1
trimethyltin(IV)chloride

: 199469-63-1
2-phenyl-5-trimethylstannylfuran

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; at -78°C to soln. of furan (ether) soln. of C4H9Li (C6H14) added,soln. stirred (N2, -78°C, 1 h; 3 h, 20°C), cooled (-78.de gree.C), Sn(CH3)3Cl in ether added dropwise via a siringe, stirred (2 h,-78°C; overnight, room temp.); mixt. quenched with aq. NH4Cl, extd. with ether (twice), ether layers dried (Na2SO4), concd. (vac.), residue distilled;
DOI:10.1039/b005948j

Reference yield:

: 108-86-1,52753-63-6
bromobenzene

: 199469-63-1
2-phenyl-5-trimethylstannylfuran

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium carbonate; palladium bis[bis(diphenylphosphino)ferrocene] dichloride / 1,4-dioxane; water / 16 h / 100 °C / Inert atmosphere

2.1: n-butyllithium / hexane; tetrahydrofuran / 2 h / -78 °C

2.2: 1 h / -78 - 20 °C

With n-butyllithium; palladium bis[bis(diphenylphosphino)ferrocene] dichloride; potassium carbonate; In tetrahydrofuran; 1,4-dioxane; hexane; water; 1.1: |Suzuki Coupling;