3-Butene-1,2-diol, 1-phenyl-, (1S,2S)-

Base Information

Chemical Name:3-Butene-1,2-diol, 1-phenyl-, (1S,2S)-
CAS No.:202589-95-5
Molecular Formula:C10H12O2
Molecular Weight:164.20100
Hs Code.:
DSSTox Substance ID:DTXSID20440282
Nikkaji Number:J890.212G
Wikidata:Q82256556

Synonyms:3-Butene-1,2-diol, 1-phenyl-, (1S,2S)-;202589-95-5;DTXSID20440282;(1S,2S)-1-Phenyl-3-butene-1,2-diol

Suppliers and Price of 3-Butene-1,2-diol, 1-phenyl-, (1S,2S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of 3-Butene-1,2-diol, 1-phenyl-, (1S,2S)-

Chemical Property:

Boiling Point:311.4±37.0 °C(Predicted)
PSA：40.46000
Density:1.120±0.06 g/cm3(Predicted)
LogP:1.26690
XLogP3:1.1
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:164.083729621
Heavy Atom Count:12
Complexity:139

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CC(C(C1=CC=CC=C1)O)O
Isomeric SMILES:C=C[C@@H]([C@H](C1=CC=CC=C1)O)O

Technology Process of 3-Butene-1,2-diol, 1-phenyl-, (1S,2S)-

There total 15 articles about 3-Butene-1,2-diol, 1-phenyl-, (1S,2S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 675834-57-8
(1S,2S)-1-phenyl-1-(tert-butyldimethylsilyloxy)but-3-en-2-ol

: 202589-95-5
(1S,2S)-1-phenyl-but-3-ene-1,2-diol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 2h;
DOI:10.1016/j.tetasy.2003.10.026

Reference yield: 91.0%

: (1S,2S)-2-[(3aR,6S,7S,7aR)-7-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yloxy]-1-phenyl-but-3-en-1-ol

: 202589-95-5
(1S,2S)-1-phenyl-but-3-ene-1,2-diol

Guidance literature:: With hydrogenchloride; In tetrahydrofuran;
DOI:10.1016/S0040-4039(97)10656-6

Reference yield:

: 167967-34-2
C₉H₁₇BO₂

: 100-52-7
benzaldehyde

: 135414-96-9
(1S,2R)-1-phenylbut-3-ene-1,2-diol

: 202589-95-5
(1S,2S)-1-phenyl-but-3-ene-1,2-diol

Guidance literature:: C₉H₁₇BO₂; With chloro-trimethyl-silane; lithium-B-H₂-(10R)-trimethylsilyl-9-borabicyclo[3.3.2]decane; In dichloromethane; at -78 - -20 ℃; Inert atmosphere;

benzaldehyde; In dichloromethane; at -78 ℃; for 4h; Inert atmosphere;

With dihydrogen peroxide; sodium hydroxide; In tetrahydrofuran; methanol; dichloromethane; water; at 20 ℃; for 12h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1016/j.tet.2011.06.008