1-[Diazo(phenyl)methyl]-4-methoxybenzene

Base Information

Chemical Name:1-[Diazo(phenyl)methyl]-4-methoxybenzene
CAS No.:20359-74-4
Molecular Formula:C14H12N2O
Molecular Weight:224.262
Hs Code.:
DSSTox Substance ID:DTXSID30514726
Nikkaji Number:J2.319.211J

Synonyms:1-[Diazo(phenyl)methyl]-4-methoxybenzene;phenyl-4-methoxyphenyldiazomethane;20359-74-4;DTXSID30514726

Suppliers and Price of 1-[Diazo(phenyl)methyl]-4-methoxybenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-[Diazo(phenyl)methyl]-4-methoxybenzene

Chemical Property:

XLogP3:3.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:224.094963011
Heavy Atom Count:17
Complexity:283

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=C(C=C1)C(=[N+]=[N-])C2=CC=CC=C2

Technology Process of 1-[Diazo(phenyl)methyl]-4-methoxybenzene

There total 3 articles about 1-[Diazo(phenyl)methyl]-4-methoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 38395-64-1
4-methoxybenzophenone hydrazone

: 20359-74-4
(4-methoxyphenyl)phenyldiazomethane

Guidance literature:: With 5,6,9,10-tetrahydro-4H,8H-pyrido[3,2,1-ij][1,6]naphthyridine; copper(II) trifluoroacetate hydrate name...; In 1,2-dichloro-ethane; at 0 ℃; for 12h; under 760.051 Torr;
DOI:10.1021/acscatal.1c00264

Reference yield:

: 611-94-9
4-Methoxybenzophenone

: 20359-74-4
(4-methoxyphenyl)phenyldiazomethane

Guidance literature:: Multi-step reaction with 2 steps

1: hydrazine hydrate; acetic acid / ethanol / 20 h / Reflux

2: magnesium sulfate; manganese(IV) oxide / dichloromethane / 0 - 20 °C

With manganese(IV) oxide; magnesium sulfate; hydrazine hydrate; acetic acid; In ethanol; dichloromethane;
DOI:10.1021/jacs.5b09888