tetrakis(tetrahydrofurane)lithium iodotris(triphenylsilyl)gallanate(-1)

Base Information

Chemical Name:tetrakis(tetrahydrofurane)lithium iodotris(triphenylsilyl)gallanate(-1)
CAS No.:361175-44-2
Molecular Formula:C₁₆H₃₂LiO₄*C₅₄H₄₅GaISi₃
Molecular Weight:1270.2
Hs Code.:

Synonyms:

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Chemical Property of tetrakis(tetrahydrofurane)lithium iodotris(triphenylsilyl)gallanate(-1)

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Technology Process of tetrakis(tetrahydrofurane)lithium iodotris(triphenylsilyl)gallanate(-1)

There total 1 articles about tetrakis(tetrahydrofurane)lithium iodotris(triphenylsilyl)gallanate(-1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 2Ga⁽¹⁺⁾*Ga₂I₆^(2-) = Ga₂(Ga₂I₆)

: 1450-23-3
hexaphenyldisilane

: 7439-93-2
lithium

: 108-88-3,15644-74-3,16713-13-6
toluene

: 361175-42-0
bis(tetrahydrofurane)lithium-iodotris(triphenylsilyl)gallanate(-1)

: 361175-44-2
tetrakis(tetrahydrofurane)lithium iodotris(triphenylsilyl)gallanate(-1)

: tetrakis(tetrahydrofurane)lithium-pentakis(triphenylsilyl)digallanate(-1)*toluene

Guidance literature:: In tetrahydrofuran; toluene; byproducts: LiI, Ga, LiI*THF; under N2; dropwise addn. of Si2Ph6 to Li in THF, stirred for 12 h, evapd. to dryness, dissolved in toluene, soln. added dropwise to suspn. of "GaI" in toluene at -78°C, stirred at this temp. for 3 h, slowly warmed to room temp.; evapd. in vac., residue extd. with pentane then with toluene and THF, crystn. of LiI(THF) and Li(THF)4Ga2(SiPh3)5 at room temp. and Li(THF)2GaI(SiPh3)3 at -20 °C from toluene fraction, Li(THF)4GaI(SiPh3)3 at -30°C from THF, elem. anal.;
DOI:10.1002/1521-3749(200107)627:7<1465::aid-zaac1465>3.0.co;2-#