[Pd(κ2-2-pyridyldiphenylphosphine)(κ1-2-pyridyldiphenylphosphine)(CF3SO3)][CF3SO3]

Base Information

• Chemical Name: [Pd(κ2-2-pyridyldiphenylphosphine)(κ1-2-pyridyldiphenylphosphine)(CF3SO3)][CF3SO3]
• CAS No.: 1246525-20-1
• Molecular Formula: CF₃O₃S*C₃₅H₂₈F₃N₂O₃P₂PdS
• Molecular Weight: 931.118
• Mol file: 1246525-20-1.mol

Synonyms:

Chemical Property of [Pd(κ2-2-pyridyldiphenylphosphine)(κ1-2-pyridyldiphenylphosphine)(CF3SO3)][CF3SO3]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(κ2-2-pyridyldiphenylphosphine)(κ1-2-pyridyldiphenylphosphine)(CF3SO3)][CF3SO3]

There total 1 articles about [Pd(κ2-2-pyridyldiphenylphosphine)(κ1-2-pyridyldiphenylphosphine)(CF3SO3)][CF3SO3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(diphenylphosphino)pyridine (37943-90-1) + trifluorormethanesulfonic acid (1493-13-6) + palladium diacetate (3375-31-3) → [Pd(κ2-2-pyridyldiphenylphosphine)(κ1-2-pyridyldiphenylphosphine)(CF3SO3)][CF3SO3] (1246525-20-1)

Guidance literature:

In dichloromethane; (N2, Schlenk) CF3SO3H was added to a soln. of Pd-compound and phosphine in CH2Cl2, the soln. was stirred for 1 h; filtered into diethyl ether, ppt. was washed three times with diethyl ether by decanted, filtered and dried in vac.; el;em. anal.;

DOI:10.1039/b918162h

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + [Pd(κ2-2-pyridyldiphenylphosphine)(κ1-2-pyridyldiphenylphosphine)(CF3SO3)][CF3SO3] (1246525-20-1) → [Pd(κ2-2-pyridyldiphenylphosphine)(κ1-2-pyridyldiphenylphosphineH)(CF3SO3)][CF3SO3]2

Guidance literature:

In dichloromethane; (N2, Schlenk) 1 equiv of CF3SO3H was added with stirring to a soln. of complex , the soln. was stirred for 1 h; filtered into diethyl ether, ppt. was washed with diethyl ether by decantation, collected by filtration and dried in vac.;

DOI:10.1039/b918162h

upstream raw materials:

2-(diphenylphosphino)pyridine

trifluorormethanesulfonic acid

palladium diacetate