TRI-n-OCTYLPHOSPHINE SELENIDE

Base Information

• Chemical Name: TRI-n-OCTYLPHOSPHINE SELENIDE
• CAS No.: 20612-73-1
• Molecular Formula: C24H51PSe
• Molecular Weight: 449.603
• Mol file: 20612-73-1.mol

Synonyms:tri-n-octylphosphine selenide;n-trioctylphosphine selenide;TOPSe;trioctylphosphine selenide;trioctylphosphineselenium;trioctylphosphine selenium;

Chemical Property of TRI-n-OCTYLPHOSPHINE SELENIDE

Chemical Property:

• PSA: 9.81000
• LogP: 9.28150

Purity/Quality:

99.9% ^*data from raw suppliers

Trioctylphosphine selenide min. 99%, (15% Se, dissolved in TOP) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRI-n-OCTYLPHOSPHINE SELENIDE

There total 2 articles about TRI-n-OCTYLPHOSPHINE SELENIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

TOP (4731-53-7) → trioctylphosphane selenide (20612-73-1)

Guidance literature:

With selenium; at 20 ℃;

DOI:10.1021/ja0656696

Reference yield:

selenium (7782-49-2) + TOP (4731-53-7) → trioctylphosphane selenide (20612-73-1)

Guidance literature:

for 48h; Inert atmosphere; Glovebox;

DOI:10.1021/ja4110182

Reference yield:

lead(II) oleate + trioctylphosphane selenide (20612-73-1) → lead(II) selenide + TOP (4731-53-7)

Guidance literature:

In further solvent(s); byproducts: tri-n-octylphosphine oxide, oleate anhydride; (C8H17)3PSe injected into soln. of Pb compd. in 1-octadecene; nanocrystals grown at 170°C over 40 min; monitored by (31)P NMR spectra;

DOI:10.1021/ja062626g

upstream raw materials:

TOP

selenium

Downstream raw materials:

TOP

copper phosphide

copper phosphide

Refernces

• 1、 Li, Ruifeng,Ye, Zhenyu,Kong, Weiguang,Wu, Huizhen,Lin, Xing,Fang, Wei. "Controllable synthesis and growth mechanism of dual size distributed PbSe quantum dots". . p. 1961 - 1967. Retrieved 2015.
• 2、 Liu, Rongjuan,Feng, Zhenyu,Cheng, Caikun,Li, Hui,Liu, Jiaming,Wei, Jingjing,Yang, Zhijie. "Active Regulation of Supramolecular Chirality through Integration of CdSe/CdS Nanorods for Strong and Tunable Circular Polarized Luminescence". supporting information. p. 2333 - 2342. Retrieved 2022/02/10.