3,6-Dihydro-4-(tributylstannyl)-1(2h)-pyridinecarboxylic acid t-butyl ester

Base Information

Chemical Name:3,6-Dihydro-4-(tributylstannyl)-1(2h)-pyridinecarboxylic acid t-butyl ester
CAS No.:208465-07-0
Molecular Formula:C22H43NO2Sn
Molecular Weight:472.299
Hs Code.:2933399090
DSSTox Substance ID:DTXSID80477433
Mol file:208465-07-0.mol

Synonyms:208465-07-0;3,6-Dihydro-4-(tributylstannyl)-1(2h)-pyridinecarboxylic acid t-butyl ester;tert-butyl 4-tributylstannyl-3,6-dihydro-2H-pyridine-1-carboxylate;3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridine carboxylic acid t-butyl ester;3,6-Dihydro-4-(tributylstannyl)-1(2h)-pyridinecarboxylic acid t-butyl ester, tech grade;4-(Tributylstannyl)-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester;tert-Butyl 4-(tributylstannyl)-3,6-dihydropyridine-1(2H)-carboxylate;tert-Butyl-4-(tributylstannyl)-5,6-dihydropyridine-1-carboxylate;C22H43NO2Sn;tert-butyl 4-(tributylstannyl)-5,6-dihydropyridine-1(2H)-carboxylate;SCHEMBL74898;DTXSID80477433;DFXDFQGKKJGPND-UHFFFAOYSA-N;MFCD18325165;4-tributylstannyl-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester;AKOS015950338;FT-0685965;A924954;J-511404;t-Butoxycarbonyl-4-Tributylstannyl-1,2,3,6-tetrahydropyridine;tert-butyl 4-tributylstannyl-3, 6-dihydro-2H-pyridine-1-carboxylate;1(2H)-Pyridinecarboxylic acid, 3,6-dihydro-4-(tributylstannyl)-, 1,1-dimethylethyl ester;3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridine carboxylic acid t-butyl ester, AldrichCPR;4-tributylstannanyl-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester

Suppliers and Price of 3,6-Dihydro-4-(tributylstannyl)-1(2h)-pyridinecarboxylic acid t-butyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridine carboxylic acid t-butyl ester
100mg
$ 150.00

TRC
3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridine carboxylic acid t-butyl ester
10mg
$ 45.00

Sigma-Aldrich
3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridine carboxylic acid t-butyl ester Aldrich
1g
$ 485.00

Matrix Scientific
3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridinecarboxylic acid t-butyl ester 94%
5g
$ 1750.00

Matrix Scientific
3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridinecarboxylic acid t-butyl ester 94%
1g
$ 681.00

Chemenu
3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridine carboxylic acid t-butyl ester 95%
1g
$ 479.00

Biosynth Carbosynth
3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridinecarboxylic acid t-butyl ester
5 g
$ 1359.80

Biosynth Carbosynth
3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridinecarboxylic acid t-butyl ester
2 g
$ 787.50

Biosynth Carbosynth
3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridinecarboxylic acid t-butyl ester
1 g
$ 498.80

American Custom Chemicals Corporation
3,6-DIHYDRO-4-(TRIBUTYLSTANNYL)-1(2H)-PYRIDINE CARBOXYLIC ACID TERT-BUTYLESTER 95.00%
5MG
$ 505.77

Total 13 raw suppliers

Chemical Property of 3,6-Dihydro-4-(tributylstannyl)-1(2h)-pyridinecarboxylic acid t-butyl ester

Chemical Property:

Boiling Point:464.392 °C at 760 mmHg
PKA:-1.44±0.40(Predicted)
Flash Point:234.656 °C
PSA：29.54000
LogP:6.87980
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:12
Exact Mass:473.231582
Heavy Atom Count:26
Complexity:432

Purity/Quality:

97% ^*data from raw suppliers

3,6-Dihydro-4-(tributylstannyl)-1(2H)-pyridine carboxylic acid t-butyl ester ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C1=CCN(CC1)C(=O)OC(C)(C)C

Technology Process of 3,6-Dihydro-4-(tributylstannyl)-1(2h)-pyridinecarboxylic acid t-butyl ester

There total 4 articles about 3,6-Dihydro-4-(tributylstannyl)-1(2h)-pyridinecarboxylic acid t-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 253429-04-8
1-(t-butoxycarbonyl)-4-hydroxy-4-tributylstannyl piperidine

: 208465-07-0
4-tributylstannanyl-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester

Guidance literature:: With methanesulfonyl chloride; triethylamine; In dichloromethane; at 0 - 20 ℃; for 5h;

Reference yield: 68.0%

: tri-n-butyltin hydride

: 79099-07-3
N-tert-butyloxycarbonylpiperidin-4-one

: 208465-07-0
4-tributylstannanyl-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester

Guidance literature:: tri-n-butyltin hydride; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at 0 ℃; for 0.333333h;

N-tert-butyloxycarbonylpiperidin-4-one; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h;

With methanesulfonyl chloride; triethylamine; In tetrahydrofuran; hexane; at 20 ℃;
DOI:10.1021/acs.joc.7b03171

Reference yield: 45.0%

: 688-73-3
tri-n-butyl-tin hydride

: 79099-07-3
N-tert-butyloxycarbonylpiperidin-4-one

: 208465-07-0
4-tributylstannanyl-3,6-dihydro-2H-pyridine-1-carboxylic acid tert-butyl ester

Guidance literature:: tri-n-butyl-tin hydride; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at 0 ℃; for 0.5h;

N-tert-butyloxycarbonylpiperidin-4-one; In tetrahydrofuran; hexane; at -78 ℃; for 2h;

With methanesulfonyl chloride; triethylamine; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 15h;
DOI:10.1016/j.ejmech.2013.12.056