4-(Tributylstannyl)-1-tritylimidazole

Base Information

• Chemical Name: 4-(Tributylstannyl)-1-tritylimidazole
• CAS No.: 208934-35-4
• Molecular Formula: C34H44N2Sn
• Molecular Weight: 599.447
• DSSTox Substance ID: DTXSID80473935
• Mol file: 208934-35-4.mol

Synonyms:4-(Tributylstannyl)-1-tritylimidazole;208934-35-4;4-(Tributylstannyl)-1-trityl-1H-imidazole;Tributyl-(1-tritylimidazol-4-yl)stannane;1H-Imidazole, 4-(tributylstannyl)-1-(triphenylmethyl)-;MFCD10699150;4-(tributylstannyl)-1-(triphenylmethyl)-1H-imidazole;C34H44N2Sn;SCHEMBL369217;DTXSID80473935;WGZVQAZCALOGIM-UHFFFAOYSA-N;AMY17573;AKOS015843075;4-Tributylstannyl-1-trityl-1H-imidazole;AS-69537;SY041737;4-Tributylstannanyl-1-trityl-1H-imidazole;1-triphenylmethyl-4-tributylstannylimidazole;CS-0088223;FT-0685449;A50102;4-(Tributylstannyl)-1-tritylimidazole, AldrichCPR;A903860;4-(tributylstannyl)-1-triphenylmethyl-1H-imidazole;J-513882

Chemical Property of 4-(Tributylstannyl)-1-tritylimidazole

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 611.6±47.0 °C(Predicted)
• PKA: 6.32±0.70(Predicted)
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 14
• Exact Mass: 600.252652
• Heavy Atom Count: 37
• Complexity: 550

Purity/Quality:

97% ^*data from raw suppliers

4-(Tributylstannyl)-1-tritylimidazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CCCC)C1=CN(C=N1)C(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of 4-(Tributylstannyl)-1-tritylimidazole

There total 7 articles about 4-(Tributylstannyl)-1-tritylimidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

ethylmagnesium bromide (925-90-6) + tributyltin chloride (1461-22-9) + ammonium chloride + N-trityl-4(5)-iodoimidazole (96797-15-8) → 4-(tributylstannyl)-1-triphenylmethyl-1H-imidazole (208934-35-4)

Guidance literature:

In diethyl ether; dichloromethane;

Reference yield: 76.0%

tributyltin chloride (1461-22-9) + N-trityl-4(5)-iodoimidazole (96797-15-8) → 4-(tributylstannyl)-1-triphenylmethyl-1H-imidazole (208934-35-4)

Guidance literature:

N-trityl-4⁽⁵⁾-iodoimidazole; With ethylmagnesium bromide; In diethyl ether; dichloromethane; at 20 ℃; for 1h; Cooling with ice;

tributyltin chloride; In diethyl ether; dichloromethane; at 20 ℃; for 2h;

Reference yield:

tributyltin chloride (1461-22-9) → 4-(tributylstannyl)-1-triphenylmethyl-1H-imidazole (208934-35-4)

Guidance literature:

N-trityl-4⁽⁵⁾-iodoimidazole; With ethylmagnesium bromide; In diethyl ether; dichloromethane; at 20 ℃; for 1h;

tributyltin chloride; In diethyl ether; dichloromethane; at 20 ℃;

upstream raw materials:

N-trityl-4⁽⁵⁾-iodoimidazole

ethylmagnesium bromide

tributyltin chloride

isopropylmagnesium bromide

Downstream raw materials:

2-(4-fluorophenyl)imidazo[1,2-a]pyridine

5-(1-tritylimidazol-4-yl)uridine

5'-O-(4-methoxytrityl)-5-(1-tritylimidazol-4-yl)uridine

2-(1-trityl-1H-imidazol-4-yl)-thiazole-5-carboxylic acid methyl ester