2-(2-bromoisobutyryloxy)ethyl methacrylate

Base Information

• Chemical Name: 2-(2-bromoisobutyryloxy)ethyl methacrylate
• CAS No.: 213453-08-8
• Molecular Formula: C10H15BrO4
• Molecular Weight: 279.12800
• Hs Code.: 2916140000
• Mol file: 213453-08-8.mol

Synonyms:BIEM;2-Methacryloxyethyl 2 inverted exclamation marka-bromoisobutyrate;2-methacryloxyethyl 2'-bromoisobutyrate;

Chemical Property of 2-(2-bromoisobutyryloxy)ethyl methacrylate

Chemical Property:

• Refractive Index: n20/D1.471
• Flash Point: >110℃
• PSA: 52.60000
• Density: 1.303 g/mL at 25 °C
• LogP: 1.82240
• Storage Temp.: 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

2-(2-Bromoisobutyryloxy)ethyl methacrylate 95% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Uses: Atom Transfer Radical Polymerization (ATRP) initiator with a methacrylate functionality for branched polymerization, orthogonal polymerization, or other functionalization.

Technology Process of 2-(2-bromoisobutyryloxy)ethyl methacrylate

There total 2 articles about 2-(2-bromoisobutyryloxy)ethyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

2-methyl-2-propenoic acid 2-hydroxyethyl ester (868-77-9,141668-69-1,25736-86-1,82601-55-6,25249-16-5) + 2-bromoisobutyric acid bromide (20769-85-1) → 2-(2-bromoisobutyryloxy)ethyl methacrylate (213453-08-8)

Guidance literature:

With pyridine; In dichloromethane; at 0 - 20 ℃; for 4.5h;

DOI:10.1021/acs.macromol.5b00278

Reference yield: 84.0%

2-methyl-2-propenoic acid 2-hydroxyethyl ester (868-77-9,141668-69-1,25736-86-1,82601-55-6,25249-16-5) + α-bromoisobutyl bromide (33693-78-6) → 2-(2-bromoisobutyryloxy)ethyl methacrylate (213453-08-8)

Guidance literature:

With triethylamine; In dichloromethane; for 1h; Cooling with ice;

DOI:10.1021/acs.macromol.7b00497

upstream raw materials:

2-methyl-2-propenoic acid 2-hydroxyethyl ester

2-bromoisobutyric acid bromide

α-bromoisobutyl bromide