1-(4-Nitrophenylsulfonyl)-2beta-benzylaziridine

Base Information

Chemical Name:1-(4-Nitrophenylsulfonyl)-2beta-benzylaziridine
CAS No.:219738-95-1
Molecular Formula:C15H14N2O4S
Molecular Weight:318.353
Hs Code.:
DSSTox Substance ID:DTXSID20440888
Nikkaji Number:J1.091.967C
Mol file:219738-95-1.mol

Synonyms:CTK0J6936;219738-95-1;1-(4-Nitrophenylsulfonyl)-2beta-benzylaziridine;DTXSID20440888

Suppliers and Price of 1-(4-Nitrophenylsulfonyl)-2beta-benzylaziridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
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Total 0 raw suppliers

Chemical Property of 1-(4-Nitrophenylsulfonyl)-2beta-benzylaziridine

Chemical Property:

XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:4
Exact Mass:318.06742811
Heavy Atom Count:22
Complexity:497

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C(N1S(=O)(=O)C2=CC=C(C=C2)[N+](=O)[O-])CC3=CC=CC=C3
Isomeric SMILES:C1[C@@H](N1S(=O)(=O)C2=CC=C(C=C2)[N+](=O)[O-])CC3=CC=CC=C3

Technology Process of 1-(4-Nitrophenylsulfonyl)-2beta-benzylaziridine

There total 4 articles about 1-(4-Nitrophenylsulfonyl)-2beta-benzylaziridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 3182-95-4
L-Phenylalaninol

: 98-74-8
4-Nitrobenzenesulfonyl chloride

: 219738-95-1
(S)-N-(p-nitrobenzenesulfonyl)-2-benzylaziridine

Guidance literature:: L-Phenylalaninol; 4-Nitrobenzenesulfonyl chloride; With pyridine; In dichloromethane; at 20 ℃; for 10h;

With potassium hydroxide; In water;
DOI:10.1016/S0040-4020(00)00666-9

Reference yield:

: 64501-87-7
2-(4-nitrophenylsulphonamido)-3-phenylpropanoic acid

: 219738-95-1
(S)-N-(p-nitrobenzenesulfonyl)-2-benzylaziridine

Guidance literature:: With methanesulfonyl chloride; triethylamine; In dichloromethane; at -20 ℃; Yield given;
DOI:10.1021/jo9815296

Reference yield:

: 63-91-2,25191-15-5,658-69-5,67675-33-6
L-phenylalanine

: 219738-95-1
(S)-N-(p-nitrobenzenesulfonyl)-2-benzylaziridine

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / LiAlH₄ / tetrahydrofuran / 0 °C

2: Et₃N / CH₂Cl₂ / 1 h / Ambient temperature

3: MsCl, Et₃N / CH₂Cl₂ / -20 °C

With lithium aluminium tetrahydride; methanesulfonyl chloride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo9815296