Technology Process of Benzenebutanal, (2,4-dinitrophenyl)hydrazone
There total 5 articles about Benzenebutanal, (2,4-dinitrophenyl)hydrazone which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C27H29N;
With
tert.-butylhydroperoxide; dirhodium caprolactamate;
In
d(4)-methanol;
at 40 ℃;
for 1.5h;
(2,4-dinitro-phenyl)-hydrazine;
In
d(4)-methanol;
at 20 ℃;
DOI:10.1021/ja3113559
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: tetra-(n-butyl)ammonium iodide; potassium hydroxide / benzene; water / 20 h / Reflux
2.1: dirhodium caprolactamate; tert.-butylhydroperoxide / d(4)-methanol / 1.5 h / 40 °C
2.2: 20 °C
With
tert.-butylhydroperoxide; dirhodium caprolactamate; tetra-(n-butyl)ammonium iodide; potassium hydroxide;
In
d(4)-methanol; water; benzene;
DOI:10.1021/ja3113559
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 20 °C / Inert atmosphere
2.1: 1H-imidazole; triphenylphosphine; iodine / tetrahydrofuran / 0.5 h / 20 °C
3.1: tetra-(n-butyl)ammonium iodide; potassium hydroxide / benzene; water / 20 h / Reflux
4.1: dirhodium caprolactamate; tert.-butylhydroperoxide / d(4)-methanol / 1.5 h / 40 °C
4.2: 20 °C
With
1H-imidazole; tert.-butylhydroperoxide; lithium aluminium tetrahydride; dirhodium caprolactamate; iodine; tetra-(n-butyl)ammonium iodide; triphenylphosphine; potassium hydroxide;
In
tetrahydrofuran; d(4)-methanol; water; benzene;
DOI:10.1021/ja3113559
