Oxiranecarboxylic acid, 3-phenyl-, ethyl ester, trans-

Base Information

Chemical Name:Oxiranecarboxylic acid, 3-phenyl-, ethyl ester, trans-
CAS No.:2272-49-3
Molecular Formula:C₁₁H₁₂O₃
Molecular Weight:192.214
Hs Code.:
DSSTox Substance ID:DTXSID801245184
Nikkaji Number:J358.855F
Mol file:2272-49-3.mol

Synonyms:ethyl (2S,3R)-3-phenyloxirane-2-carboxylate;Oxiranecarboxylic acid, 3-phenyl-, ethyl ester, trans-;2272-55-1;DTXSID801245184;rel-Ethyl (2R,3R)-3-phenyl-2-oxiranecarboxylate;3alpha-Phenyloxirane-2alpha-carboxylic acid ethyl ester;2272-49-3

Suppliers and Price of Oxiranecarboxylic acid, 3-phenyl-, ethyl ester, trans-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 5 raw suppliers

Chemical Property of Oxiranecarboxylic acid, 3-phenyl-, ethyl ester, trans-

Chemical Property:

XLogP3:1.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:192.078644241
Heavy Atom Count:14
Complexity:209

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCOC(=O)C1C(O1)C2=CC=CC=C2
Isomeric SMILES:CCOC(=O)[C@@H]1[C@@H](O1)C2=CC=CC=C2

Technology Process of Oxiranecarboxylic acid, 3-phenyl-, ethyl ester, trans-

There total 43 articles about Oxiranecarboxylic acid, 3-phenyl-, ethyl ester, trans- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 146452-40-6
(2R,3R) ethyl 2-chloro-3-hydroxy-3-phenylpropionate

: 121-39-1,2272-49-3,2272-55-1,54276-44-7,56791-22-1,126060-73-9,130321-77-6,130321-78-7,130605-53-7
(2S,3R)-ethyl 3-phenyloxirane-2-carboxylate

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1016/0040-4039(95)00182-C

Reference yield: 87.0%

: 1152-30-3,109463-49-2,109463-48-1
(E)-ethyl 4-styrylbenzoate

: 121-39-1,2272-49-3,2272-55-1,54276-44-7,56791-22-1,126060-73-9,130321-77-6,130321-78-7,130605-53-7
(2S,3R)-ethyl 3-phenyloxirane-2-carboxylate

Guidance literature:: With (5S,8R,9R)-2,2-dimethyl-10-oxo-1,3,6-trioxaspiro[4.5]decane-8,9-diyl diacetate; Na₂EDTA; oxone; tetra(n-butyl)ammonium hydrogensulfate; sodium hydrogencarbonate; In water; acetonitrile; at 28 ℃; for 24h; pH=7 - 8; optical yield given as %ee;
DOI:10.1002/adsc.201100735

Reference yield: 73.0%

: 4192-77-2
ethyl cinnamate

: 121-39-1,2272-49-3,2272-55-1,54276-44-7,56791-22-1,126060-73-9,130321-77-6,130321-78-7,130605-53-7
(2S,3R)-ethyl 3-phenyloxirane-2-carboxylate

Guidance literature:: With Oxone; edetate disodium; sodium hydrogencarbonate; (5S,8R,9R)-c(C(O)C(c(OC(CH₃)2OCH₂))OCH₂CHOAcCHOAc); tetra(n-butyl)ammonium hydrogensulfate; In acetonitrile; at 0 - 20 ℃; for 24h;
DOI:10.1021/ja020478y