ruthenium3(carbonyl)11{(phenyl)2PCC(tert-butyl)}

Base Information

Chemical Name:ruthenium3(carbonyl)11{(phenyl)2PCC(tert-butyl)}
CAS No.:110511-62-1
Molecular Formula:C₂₉H₁₉O₁₁PRu₃
Molecular Weight:877.647
Hs Code.:

Synonyms:

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Chemical Property of ruthenium3(carbonyl)11{(phenyl)2PCC(tert-butyl)}

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Technology Process of ruthenium3(carbonyl)11{(phenyl)2PCC(tert-butyl)}

There total 1 articles about ruthenium3(carbonyl)11{(phenyl)2PCC(tert-butyl)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 33730-51-7
(3,3-dimethyl-1-butynyl)diphenylphosphine

: 110511-62-1
ruthenium3(carbonyl)11{(phenyl)2PCC(tert-butyl)}

Guidance literature:: In tetrahydrofuran; Under N2, Ru3(CO)12, THF and PPh2CC(t-Bu) are added, with rapid stirring a catalytic amt. of Na-benzophenone ketyl soln. is added. Stirring approx. 5 min.; Concg., resulting sludge is dild. with heptane, mixt. again concd., chromd. on Florisil column. Elution with heptane. Elem. anal.;

Reference yield:

: 110511-62-1
ruthenium3(carbonyl)11{(phenyl)2PCC(tert-butyl)}

: 77700-86-8
ruthenium3(carbonyl)9{μ3-η2-(tert-butyl-acetylide)}(μ-phosphido(phenyl)2)

Guidance literature:: In tetrahydrofuran; Addn. of THF to Ru3(CO)11(PPh2CC(t-Bu)), dilg. with THF, (room temp.) and bubbling N2 through the soln. (10-11 d).;

Reference yield:

: 110511-62-1
ruthenium3(carbonyl)11{(phenyl)2PCC(tert-butyl)}

: 1184-78-7
trimethylamine-N-oxide

: 77700-86-8
ruthenium3(carbonyl)9{μ3-η2-(tert-butyl-acetylide)}(μ-phosphido(phenyl)2)

Guidance literature:: In ethanol; n-heptane; Under N2, heptane soln. of Ru3(CO)11PPh2CC(t-Bu))is cooled (-10°C), addn. of Me3NO in abs. EtOH.; Evacuating and storing at -10°C overnight, decanting of mather liquor from ppt., addn. of Me3NO, again evacuating and storing at -10°C overnight, recrystn. of combined solids from heptane under CO, elem. anal.;