9,10-Ph₂-1,7-(Me₂S)2B₁₂H₈

Base Information

Chemical Name:9,10-Ph₂-1,7-(Me₂S)2B₁₂H₈
CAS No.:531509-69-0
Molecular Formula:C₁₆H₃₀B₁₂S₂
Molecular Weight:416.278
Hs Code.:

9,10-Ph<sub>2</sub>-1,7-(Me<sub>2</sub>S)2B<sub>12</sub>H<sub>8</sub>

Synonyms:

Suppliers and Price of 9,10-Ph₂-1,7-(Me₂S)2B₁₂H₈

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 9,10-Ph₂-1,7-(Me₂S)2B₁₂H₈

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 9,10-Ph₂-1,7-(Me₂S)2B₁₂H₈

There total 1 articles about 9,10-Ph₂-1,7-(Me₂S)2B₁₂H₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 531509-54-3
9,10-I₂-1,7-(Me₂S)2B₁₂H₈

: 100-58-3
phenylmagnesium bromide

: 531509-69-0
9,10-Ph₂-1,7-(Me₂S)2B₁₂H₈

Guidance literature:: bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; THF condensed to B compd. and Pd complex (4-5 mol%); stirred for 30 min in ice-water bath; soln. of PhMgBr (excess) in ether added; heated at 40-45°C (oil bath) for 1-2 d; MeOH added; monitored by (11)B NMR spectra; solvent removed in vac.; partitioned between CH2Cl2-aq. HCl; org. phase washed with distd. water; dried (MgSO4);filtered; solvent removed under reduced pressure; purified by chromy.;
DOI:10.1021/ic020600u