Isocyanato(dimethyl)phenylsilane

Base Information

• Chemical Name: Isocyanato(dimethyl)phenylsilane
• CAS No.: 23115-25-5
• Molecular Formula: C9H11NOSi
• Molecular Weight: 177.278
• DSSTox Substance ID: DTXSID20508351
• Nikkaji Number: J1.198.762A
• Mol file: 23115-25-5.mol

Synonyms:Isocyanato(dimethyl)phenylsilane;23115-25-5;SCHEMBL10667324;DTXSID20508351

Chemical Property of Isocyanato(dimethyl)phenylsilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 177.060990509
• Heavy Atom Count: 12
• Complexity: 191

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C1=CC=CC=C1)N=C=O

Technology Process of Isocyanato(dimethyl)phenylsilane

There total 9 articles about Isocyanato(dimethyl)phenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

phenyldimethylsilyl chloride (768-33-2) + urea (57-13-6) → isocyanatodimethylphenylsilane (23115-25-5) + Bis-(dimethyl-phenyl-silyl)-carbodiimid (18002-53-4)

Guidance literature:

With 1,1,1,3,3,3-hexamethyl-disilazane; at 190 ℃; for 6h;

Reference yield:

Dimethylphenylsilane (766-77-8) + urea (57-13-6) → isocyanatodimethylphenylsilane (23115-25-5) + 1,1,3,3-tetramethyl-1,3-diphenyldisiloxane (56-33-7)

Guidance literature:

In 1,3,5-trimethyl-benzene; at 145 ℃; for 5h; under 760.051 Torr; Temperature; Solvent; Time; Glovebox; Inert atmosphere; Green chemistry;

DOI:10.1002/anie.201303132

Reference yield:

Dimethylphenylsilane (766-77-8) + urea (57-13-6) → isocyanatodimethylphenylsilane (23115-25-5) + dimethylphenylsilanol (5272-18-4) + 1,1,3,3-tetramethyl-1,3-diphenyldisiloxane (56-33-7)

Guidance literature:

With gold-ceria nanoparticle; silica gel; In toluene; at 135 ℃; for 1h; under 760.051 Torr; Glovebox; Inert atmosphere; Green chemistry;

DOI:10.1002/anie.201303132

upstream raw materials:

1,1,3,3-tetramethyl-1,3-diphenyldisilazane

phenyl isocyanate

phenyldimethylsilyl chloride

urea

Downstream raw materials:

(dimethylphenylsiloxy)methyl isocyanate

N-(dimethylphenylsilyl)-N'-(trimethylsiloxy)urea