Propane-1-sulfinyl chloride

Base Information

• Chemical Name: Propane-1-sulfinyl chloride
• CAS No.: 23267-68-7
• Molecular Formula: C3H7ClOS
• Molecular Weight: 126.607
• DSSTox Substance ID: DTXSID80509006
• Nikkaji Number: J582.172J
• Mol file: 23267-68-7.mol

Synonyms:23267-68-7;PROPANE-1-SULFINYL CHLORIDE;1-Propanesulfinyl chloride;Propane-1-sulfinic Chloride;propanesulfinyl chloride;SCHEMBL2645410;DTXSID80509006;PROPANE-1-SULFINYLCHLORIDE;MFCD28118495;SY359055;EN300-184463

Chemical Property of Propane-1-sulfinyl chloride

Chemical Property:

• PSA: 36.28000
• LogP: 2.16460
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 125.9906137
• Heavy Atom Count: 6
• Complexity: 54.8

Purity/Quality:

propane-1-sulfinylchloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCS(=O)Cl

Technology Process of Propane-1-sulfinyl chloride

There total 10 articles about Propane-1-sulfinyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

diphenyl-di-n-propyltin(IV) (23668-80-6) → propane-1-sulfinyl chloride (23267-68-7) + diphenyltin(IV) dichloride (1135-99-5)

Guidance literature:

With thionyl chloride; from 0 deg C up to room temp.; reflux, 30 min;

Reference yield: 92.0%

thionyl chloride (7719-09-7) + diphenyl-di-n-propyltin(IV) (23668-80-6) → propane-1-sulfinyl chloride (23267-68-7) + diphenyltin(IV) dichloride (1135-99-5)

Guidance literature:

In not given; dropwise addn. of thionyl chloride to tetraalkyltin(IV) compd. under dry N2 atmosphere under ice cooling, warming to room temp., refluxing for 30 min; distn. (removal of excess of SOCl2), cooling resulting liquids, sepn., elem. anal.;

Reference yield: 90.0%

tetrapropylstannane (2176-98-9) → propane-1-sulfinyl chloride (23267-68-7) + di(n-propyl)tin dichloride (867-36-7)

Guidance literature:

With thionyl chloride; from 0 deg C up to room temp.; reflux, 30 min;

upstream raw materials:

1-thiopropane

1-propyl 2-(trimethylsilyl)ethyl sulfoxide

tetrapropylstannane

diphenyl-di-n-propyltin(IV)

Downstream raw materials:

thiopropanal S-oxide

propyl propylthiosulfonate

Propanethiosulfonic acid S-(1-chloro-propyl) ester

(Z)-propanethial S-oxide