9-Borabicyclo[3.3.1]nonane, 9-methyl-

Base Information

• Chemical Name: 9-Borabicyclo[3.3.1]nonane, 9-methyl-
• CAS No.: 23418-81-7
• Molecular Formula: C9H17B
• Molecular Weight: 136.045
• Mol file: 23418-81-7.mol

Synonyms:

Chemical Property of 9-Borabicyclo[3.3.1]nonane, 9-methyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-Borabicyclo[3.3.1]nonane, 9-methyl-

There total 7 articles about 9-Borabicyclo[3.3.1]nonane, 9-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

diiron nonacarbonyl (15321-51-4) + 9-bora-bicyclo[3.3.1]nonane (280-64-8) → 9-butyl-9-borabicyclo<3.3.1>nonane (23532-74-3) + 9-pentyl-9-borobicyclononane (318290-86-7) + 9-hexyl-9-borabicyclo[3.3.1]nonane (42371-64-2) + 9-methyl-9-borabicyclo[3.3.1]nonane (23418-81-7) + 9-heptyl-9-borabicyclo<3,3,1>nonane (72245-81-9)

Guidance literature:

In further solvent(s); byproducts: H2, CH4, C2H6; a suspension of 9-BBN and Fe2(CO)9 in nonane was slowly heated to above140°C (bath temp.) under an inert gas atm.; stirring for about 0.5 h; further products and byproducts; mechanism discussed;; distn. under vac.; mixt. of 9-alkyl-9-BBN obtained, detected by GC/MS;;

Reference yield: 46.7%

triiron dodecarbonyl (17685-52-8) + 9-bora-bicyclo[3.3.1]nonane (280-64-8) → 9-butyl-9-borabicyclo<3.3.1>nonane (23532-74-3) + 9-pentyl-9-borobicyclononane (318290-86-7) + 9-hexyl-9-borabicyclo[3.3.1]nonane (42371-64-2) + 9-methyl-9-borabicyclo[3.3.1]nonane (23418-81-7) + 9-heptyl-9-borabicyclo<3,3,1>nonane (72245-81-9)

Guidance literature:

In further solvent(s); byproducts: H2, CH4, C2H6; a suspension of 9-BBN and Fe3(CO)12 in nonane was slowly heated to above 130°C (bath temp.) under an inert gas atm.; stirring for about 0.5 h; further products and byproducts; mechanism discussed;; distn. under vac.; mixt. of 9-alkyl-9-BBN obtained, detected by GC/MS;;

Reference yield: 42.9%

iron pentacarbonyl (13463-40-6,37220-42-1) + 9-bora-bicyclo[3.3.1]nonane (280-64-8) → 9-butyl-9-borabicyclo<3.3.1>nonane (23532-74-3) + 9-pentyl-9-borobicyclononane (318290-86-7) + 9-hexyl-9-borabicyclo[3.3.1]nonane (42371-64-2) + 9-methyl-9-borabicyclo[3.3.1]nonane (23418-81-7) + 9-heptyl-9-borabicyclo<3,3,1>nonane (72245-81-9)

Guidance literature:

In further solvent(s); byproducts: H2, CH4, C4H10; a suspension of 9-BBN and Fe(CO)5 in nonane was slowly heated to about 140°C (bath temp.) under an inert gas atm.; stirring for about 0.5 h; further products and byproducts; mechanism discussed;; distn. under vac.; mixt. of 9-alkyl-9-BBN obtained, detected by GC/MS;;

upstream raw materials:

9-chloro-9-borabicyclo{3.3.1}nonane

triiron dodecarbonyl

9-bora-bicyclo[3.3.1]nonane

iron pentacarbonyl

Downstream raw materials:

4-methyl-benzoic acid methyl ester

(S)-3-Eth-(Z)-ylidene-5-trityloxymethyl-dihydro-furan-2-one