Methanaminium, N-(chlorophenylmethylene)-N-methyl-, chloride

Base Information

• Chemical Name: Methanaminium, N-(chlorophenylmethylene)-N-methyl-, chloride
• CAS No.: 2397-26-4
• Molecular Formula: C9H11ClN.Cl
• Molecular Weight: 204.099
• DSSTox Substance ID: DTXSID80449650
• Mol file: 2397-26-4.mol

Synonyms:2397-26-4;Methanaminium, N-(chlorophenylmethylene)-N-methyl-, chloride;SCHEMBL7473437;DTXSID80449650;GGIRGRHHZRLDGX-UHFFFAOYSA-M;(alpha-chlorobenzylidene)dimethylammonium chloride;N-(chloro(phenyl)methylene)-N-methylmethanaminium chloride

Chemical Property of Methanaminium, N-(chlorophenylmethylene)-N-methyl-, chloride

Chemical Property:

• Melting Point: 124-125 °C
• PSA: 3.24000
• LogP: -1.72050
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 203.0268547
• Heavy Atom Count: 12
• Complexity: 153

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[N+](=C(C1=CC=CC=C1)Cl)C.[Cl-]

Technology Process of Methanaminium, N-(chlorophenylmethylene)-N-methyl-, chloride

There total 1 articles about Methanaminium, N-(chlorophenylmethylene)-N-methyl-, chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N,N-dimethylbenzamide (611-74-5) → N,N-dimethyl(chlorophenylmethylene)ammonium chloride (2397-26-4)

Guidance literature:

With toluene; Einleiten von Phosgen und eintaegiges Aufbewahren des Reaktionsgemisches bei 20grad;

Reference yield: 94.0%

N,N-dimethyl(chlorophenylmethylene)ammonium chloride (2397-26-4) + methyl O-(methyl 4,5:7,8-di-O-isopropylidene-α-D-glycero-D-talo-2-octulopyranosonate)-(2->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside (271245-11-5) → methyl O-(methyl 4,5:7,8-di-O-isopropylidene-3-O-thiobenzoyl-α-D-glycero-D-talo-2-octulopyranosonate)-(2->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside (271245-12-6)

Guidance literature:

N,N-dimethyl(chlorophenylmethylene)ammonium chloride; methyl O-(methyl 4,5:7,8-di-O-isopropylidene-α-D-glycero-D-talo-2-octulopyranosonate)-(2->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside; With pyridine; In dichloromethane; at 20 ℃; for 24h;

With pyridine; hydrogen sulfide; In dichloromethane;

DOI:10.1016/S0957-4166(99)00557-1

Reference yield: 94.0%

N,N-dimethyl(chlorophenylmethylene)ammonium chloride (2397-26-4) + thexyldimethylsilyl O-(methyl 4,5:7,8-di-O-isopropylidene-α-D-glycero-D-talo-2-octulopyranosonate)-(2->6)-2-azido-3,4-di-O-benzyl-2-deoxy-β-D-glucopyranoside (271245-15-9) → thexyldimethylsilyl O-(methyl 4,5:7,8-di-O-isopropylidene-3-O-thiobenzoyl-α-D-glycero-D-talo-2-octulopyranosonate)-(2->6)-2-azido-3,4-di-O-benzyl-2-deoxy-β-D-glucopyranoside (271245-16-0)

Guidance literature:

N,N-dimethyl(chlorophenylmethylene)ammonium chloride; thexyldimethylsilyl O-(methyl 4,5:7,8-di-O-isopropylidene-α-D-glycero-D-talo-2-octulopyranosonate)-(2->6)-2-azido-3,4-di-O-benzyl-2-deoxy-β-D-glucopyranoside; With pyridine; In dichloromethane; at 20 ℃; for 24h;

With pyridine; hydrogen sulfide; In dichloromethane; for 0.0833333h;

DOI:10.1016/S0957-4166(99)00557-1

upstream raw materials:

N,N-dimethylbenzamide

Downstream raw materials:

N-cicloesil-α-ossofenilacetamide

α,α-diethoxy-N,N-dimethylbenzenemethanamine

N-n-butyl-2-oxo-2-phenylacetamide

N,N-dimethylthiobenzamide