1,1'-Biphenyl, 3,3'-bis(bromomethyl)-

Base Information

Chemical Name:1,1'-Biphenyl, 3,3'-bis(bromomethyl)-
CAS No.:24656-53-9
Molecular Formula:C14H12Br2
Molecular Weight:340.057
Hs Code.:2903999090
DSSTox Substance ID:DTXSID60404989
Nikkaji Number:J338.076I
Wikidata:Q82209360
Mol file:24656-53-9.mol

Synonyms:3,3'-bis(bromomethyl)-1,1'-biphenyl;1,1'-Biphenyl, 3,3'-bis(bromomethyl)-;3,3'-bis(bromomethyl)biphenyl;SCHEMBL1259618;DTXSID60404989;RAFYFUWHDWAUKS-UHFFFAOYSA-N;AKOS024331733

Suppliers and Price of 1,1'-Biphenyl, 3,3'-bis(bromomethyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
3,3'-BIS-BROMOMETHYL-BIPHENYL Aldrich
25mg
$ 144.00

American Custom Chemicals Corporation
3,3'-BIS-BROMOMETHYL-BIPHENYL 95.00%
5MG
$ 502.77

Total 2 raw suppliers

Chemical Property of 1,1'-Biphenyl, 3,3'-bis(bromomethyl)-

Chemical Property:

Melting Point:119-120 °C
Boiling Point:391.0±27.0 °C(Predicted)
PSA：0.00000
Density:1.591±0.06 g/cm3(Predicted)
LogP:5.14340
XLogP3:4.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:339.92853
Heavy Atom Count:16
Complexity:183

Purity/Quality:

98% ^*data from raw suppliers

3,3'-BIS-BROMOMETHYL-BIPHENYL Aldrich ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=CC(=C1)C2=CC=CC(=C2)CBr)CBr

Technology Process of 1,1'-Biphenyl, 3,3'-bis(bromomethyl)-

There total 5 articles about 1,1'-Biphenyl, 3,3'-bis(bromomethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 612-75-9
3,3'-dimethyl-biphenyl

: 24656-53-9
3,3'-bis(bromomethyl)biphenyl

Guidance literature:: With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); In tetrachloromethane; for 18h; Reflux; Inert atmosphere;
DOI:10.1016/j.bmcl.2011.11.017

Reference yield: 64.0%

: 66888-79-7
biphenyl-3,3′-diyldimethanol

: 24656-53-9
3,3'-bis(bromomethyl)biphenyl

Guidance literature:: With phosphorus tribromide; In chloroform; for 2h; Ambient temperature;
DOI:10.1021/jo980441p

Reference yield:

: 3132-99-8
m-bromobenzoic aldehyde

: 24656-53-9
3,3'-bis(bromomethyl)biphenyl

Guidance literature:: Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / 1,4-dioxane; water / 16 h / 85 °C / Inert atmosphere

2: methanol; sodium tetrahydroborate / 2 h / 0 °C

3: triphenylphosphine; N-Bromosuccinimide / dichloromethane / 2 h / 0 °C

With methanol; sodium tetrahydroborate; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; triphenylphosphine; In 1,4-dioxane; dichloromethane; water;