Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy-

Base Information

Chemical Name:Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy-
CAS No.:2467-07-4
Molecular Formula:C23H32O4
Molecular Weight:372.505
Hs Code.:
DSSTox Substance ID:DTXSID30411963
Nikkaji Number:J1.490.712B
Wikidata:Q82219058

Synonyms:Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy-;2467-07-4;SCHEMBL21260626;DTXSID30411963

Suppliers and Price of Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy-

Chemical Property:

XLogP3:5.8
Hydrogen Bond Donor Count:4
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:372.23005950
Heavy Atom Count:27
Complexity:422

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)C1=CC(=C(C(=C1)CO)O)CC2=C(C(=CC(=C2)C(C)(C)C)CO)O

Technology Process of Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy-

There total 8 articles about Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 35851-06-0
3-(5-tert-Butylsalicyl)-5-tert-butyl-2-hydroxybenzyl Alcohol

: 2467-07-4
bis(5-tert-butyl-2-hydroxy-3-hydroxymethyl-phenyl)methane

Guidance literature:: With sodium hydroxide; In methanol; at 50 ℃; for 24h;
DOI:10.1021/jo00157a033

Reference yield: 29.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 98-54-4
para-tert-butylphenol

: 2467-07-4
bis(5-tert-butyl-2-hydroxy-3-hydroxymethyl-phenyl)methane

Guidance literature:: With sodium hydroxide; at 45 - 55 ℃; for 168h;
DOI:10.1021/jo00157a033

Reference yield:

: 6638-87-5
4-(tert-butyl)-2-(hydroxymethyl)phenol

: 2467-07-4
bis(5-tert-butyl-2-hydroxy-3-hydroxymethyl-phenyl)methane

Guidance literature:: Multi-step reaction with 3 steps

1: toluene-4-sulfonic acid / 72 h / 120 °C

2: trifluoroacetic acid / 48 h / 90 °C

3: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / 20 °C / Inert atmosphere; Schlenk technique; Reflux

With lithium aluminium tetrahydride; toluene-4-sulfonic acid; trifluoroacetic acid; In tetrahydrofuran; 2: |Duff Aldehyde Synthesis;
DOI:10.1055/s-0036-1589127