2,6-Dibromo-3-(2,4-dibromophenoxy)phenol

Base Information

Chemical Name:2,6-Dibromo-3-(2,4-dibromophenoxy)phenol
CAS No.:24949-31-3
Molecular Formula:C12H6Br4O2
Molecular Weight:501.794
Hs Code.:
DSSTox Substance ID:DTXSID00903986
Nikkaji Number:J2.010.496A
Wikidata:Q27467826
Mol file:24949-31-3.mol

Synonyms:2,6-dibromo-3-(2,4-dibromophenoxy)phenol;DTXSID00903986;3-hydroxy-2,2',4,4'-tetrabromodiphenyl ether;Q27467826;24949-31-3

Suppliers and Price of 2,6-Dibromo-3-(2,4-dibromophenoxy)phenol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 2,6-Dibromo-3-(2,4-dibromophenoxy)phenol

Chemical Property:

XLogP3:5.9
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:501.70603
Heavy Atom Count:18
Complexity:279

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=C(C=C1Br)Br)OC2=C(C(=C(C=C2)Br)O)Br

Technology Process of 2,6-Dibromo-3-(2,4-dibromophenoxy)phenol

There total 2 articles about 2,6-Dibromo-3-(2,4-dibromophenoxy)phenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 602326-18-1
3′-hydroxy-2,4-dibromodiphenyl ether

: 24949-30-2
3′-hydroxy-2,4,4′-tribromodiphenyl ether

: 24949-31-3
3-hydroxy-2,2′,4,4′-tetrabromodiphenylether

Guidance literature:: With bromine; tert-butylamine; In dichloromethane; toluene; at -70 - -60 ℃; for 6h;
DOI:10.1002/ejoc.200300081

Reference yield:

: 602326-17-0
3-(2,4-dibromophenoxy)benzaldehyde

: 24949-31-3
3-hydroxy-2,2′,4,4′-tetrabromodiphenylether

Guidance literature:: Multi-step reaction with 2 steps

1.1: KH₂PO₄; CF₃CO₃H / CH₂Cl₂ / 2 h / 0 °C

1.2: 83 percent / hydrochloric acid / methanol / 15 h

2.1: 50 percent / bromine; tert-butylamine / CH₂Cl₂; toluene / 6 h / -70 - -60 °C

With potassium dihydrogenphosphate; trifluoroacetyl peroxide; bromine; tert-butylamine; In dichloromethane; toluene; 1.1: Baeyer-Villiger oxidation;
DOI:10.1002/ejoc.200300081

Reference yield: 99.0%

: 24949-31-3
3-hydroxy-2,2′,4,4′-tetrabromodiphenylether

: 74-88-4
methyl iodide

: 3-methoxy-2,2',4,4'-tetrabromodiphenyl ether

Guidance literature:: With sodium hydroxide; tetra(n-butyl)ammonium hydroxide; In dichloromethane; water; at 20 ℃; for 5h;
DOI:10.1002/ejoc.200300081