(E)-1-(Cyclohex-1-en-1-yl)-2-(4-nitrophenyl)diazene

Base Information

• Chemical Name: (E)-1-(Cyclohex-1-en-1-yl)-2-(4-nitrophenyl)diazene
• CAS No.: 25769-31-7
• Molecular Formula: C12H13N3O2
• Molecular Weight: 231.254
• DSSTox Substance ID: DTXSID50493089
• Mol file: 25769-31-7.mol

Synonyms:25769-31-7;(E)-1-(Cyclohex-1-en-1-yl)-2-(4-nitrophenyl)diazene;DTXSID50493089;1-nitro-4-(cyclohexen-1-ylazo)benzene

Chemical Property of (E)-1-(Cyclohex-1-en-1-yl)-2-(4-nitrophenyl)diazene

Chemical Property:

• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 231.100776666
• Heavy Atom Count: 17
• Complexity: 325

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(=CC1)N=NC2=CC=C(C=C2)[N+](=O)[O-]

Technology Process of (E)-1-(Cyclohex-1-en-1-yl)-2-(4-nitrophenyl)diazene

There total 2 articles about (E)-1-(Cyclohex-1-en-1-yl)-2-(4-nitrophenyl)diazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

4-nitrophenylhydrazone (100-16-3) + 2-Chlorocyclohexanone (822-87-7) → (E)-1-(cyclohex-1-en-1-yl)-2-(4-nitrophenyl)diazene (25769-31-7)

Guidance literature:

2-Chlorocyclohexanone; With pyridine; at 100 ℃; for 0.0833333h;

4-nitrophenylhydrazone; In tetrahydrofuran; at 0 ℃; for 2h;

DOI:10.1021/jacs.5b04518

Reference yield:

→ <(p-nitrophenyl)azo>cyclohexene (25769-31-7)

Guidance literature:

2-Pyridinio-cyclohexanon-(1)--chlorid, W., 2n-NaOH, 0grad, Extraktion m. Chlf., Entfernen d. Lsgsm. b. 50grad/0.01 Torr;

Reference yield: 94.0%

anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) + <(p-nitrophenyl)azo>cyclohexene (25769-31-7) → 2-{2-[(4-Nitro-phenyl)-hydrazono]-cyclohexylamino}-benzoic acid (92925-39-8)

Guidance literature:

CuCl₂*2H₂O; In tetrahydrofuran; for 1h; Ambient temperature;

DOI:10.1055/s-1984-30860

upstream raw materials:

4-nitrophenylhydrazone

2-Chlorocyclohexanone

Downstream raw materials:

3-(4-nitro-phenyl)-1-(toluene-4-sulfonyl)-3,5,6,7,8,8a-hexahydro-1H-benzo[1,2,3,6]thiatriazine 2-oxide

1-(p-nitrophenylamino)-2-methyl-3-carbethoxy-4,5,6,7-tetrahydroindole

4-{2-[(4-Nitro-phenyl)-hydrazono]-cyclohexylamino}-benzoic acid

2-{2-[(4-Nitro-phenyl)-hydrazono]-cyclohexylamino}-benzoic acid