[Cp₂Hf(2-(di-tert-butylphosphino)phenoxide)]B(C₆F₅)4

Base Information

• Chemical Name: [Cp₂Hf(2-(di-tert-butylphosphino)phenoxide)]B(C₆F₅)4
• CAS No.: 1309604-66-7
• Molecular Formula: C₂₄BF₂₀*C₂₄H₃₂HfOP
• Molecular Weight: 1225.02
• Mol file: 1309604-66-7.mol

Synonyms:

Chemical Property of [Cp₂Hf(2-(di-tert-butylphosphino)phenoxide)]B(C₆F₅)4

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Cp₂Hf(2-(di-tert-butylphosphino)phenoxide)]B(C₆F₅)4

There total 1 articles about [Cp₂Hf(2-(di-tert-butylphosphino)phenoxide)]B(C₆F₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(cyclopentadienyl)hafnium dimethyl + 2,6-di-tert-butylpyridininum tetrakis(pentafluorophenyl)borate (1309604-77-0) + di-tert-butyl-(2-hydroxyphenyl)phosphane (57542-89-9) → [Cp2Hf(2-(di-tert-butylphosphino)phenoxide)]B(C6F5)4 (1309604-66-7)

Guidance literature:

In hexane; chlorobenzene; Ar, Schlenk-line and glovebox; reaction of Hf-complex with phosphine in hexane at 25 °C for 1 d followed by reaction with pyridinium saltin C6H5Cl at 25 °C for 3 d according to A.M.Chapman et al. J. Am . Chem. Soc. 2011, 133, 18463;

DOI:10.1002/ejic.201100968

upstream raw materials:

2,6-di-tert-butylpyridininum tetrakis(pentafluorophenyl)borate

di-tert-butyl-(2-hydroxyphenyl)phosphane