2-(Allyloxy)aniline

Base Information

• Chemical Name: 2-(Allyloxy)aniline
• CAS No.: 27096-64-6
• Molecular Formula: C9H11NO
• Molecular Weight: 149.192
• Hs Code.: 2922299090
• DSSTox Substance ID: DTXSID50424570
• Nikkaji Number: J1.565.248I
• Wikidata: Q82237207
• Mol file: 27096-64-6.mol

Synonyms:2-(ALLYLOXY)ANILINE;27096-64-6;2-Allyloxy-phenylamine;2-prop-2-enoxyaniline;2-allyloxyaniline;2-(prop-2-en-1-yloxy)aniline;AKOS BBB/400;2-(2-Propenyloxy)-benzenamine;SCHEMBL4608367;DTXSID50424570;VPZRVYLJWAJQRE-UHFFFAOYSA-N;HMS1704C12;BBL023219;MFCD01902258;STL066884;AKOS000301155;NCGC00326351-01;FT-0758593;AB01321183-02

Chemical Property of 2-(Allyloxy)aniline

Chemical Property:

• Vapor Pressure: 0.0138mmHg at 25°C
• Boiling Point: 258.3oC at 760 mmHg
• PKA: 4.48±0.10(Predicted)
• Flash Point: 116oC
• PSA: 35.25000
• Density: 1.037g/cm3
• LogP: 2.41480
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 149.084063974
• Heavy Atom Count: 11
• Complexity: 125

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCOC1=CC=CC=C1N

Technology Process of 2-(Allyloxy)aniline

There total 13 articles about 2-(Allyloxy)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-allyloxy-1-nitrobenzene (55339-51-0) → 2-(allyloxy)aniline (27096-64-6)

Guidance literature:

With hydrogenchloride; tin(ll) chloride; In ethanol; water;

DOI:10.1002/chem.201300354

Reference yield: 95.0%

2-Acetylamino-phenyl-allyl-ether (91132-57-9) → 2-(allyloxy)aniline (27096-64-6)

Guidance literature:

With hydrogenchloride; In water; for 4h; Reflux;

DOI:10.1021/acs.orglett.0c00823

Reference yield: 87.0%

→ 2-(allyloxy)aniline (27096-64-6)

Guidance literature:

With trichlorosilane; triethylamine; In acetonitrile; at 15 ℃; for 18h;

upstream raw materials:

2-allyloxy-1-nitrobenzene

2-Acetylamino-phenyl-allyl-ether

2-(acetylamino)phenol

o-(prop-2-enyloxy)phenyl azide

Downstream raw materials:

N-[2-(allyloxy)phenyl]-4-methylbenzenesulfonamide

6-Acetylamino-2-allyl-phenol

acetic acid-(5-allyl-2-hydroxy-anilide)

4-Allyl-2-amino-phenol