55339-51-0

Basic information

• Product Name: Allyl 2-nitrophenyl ether
• Synonyms: 1-(Allyloxy)-2-nitrobenzene;1-Nitro-2-(allyloxy)benzene;1-Nitro-2-allyloxybenzene;Allyl 2-nitrophenyl ether;Allyl(2-nitrophenyl) ether
• CAS NO: 55339-51-0
• Molecular Formula: C₉H₉NO₃
• Molecular Weight: 179.17266
• Mol File: 55339-51-0.mol
• Article Data: 35

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Allyl 2-nitrophenyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: Allyl 2-nitrophenyl ether(55339-51-0)
• EPA Substance Registry System: Allyl 2-nitrophenyl ether(55339-51-0)

Safety Data

• Hazardous Substances Data: 55339-51-0(Hazardous Substances Data)

Usage

Chemical structure

nitrophenyl ether derivative with an allyl group attached to the phenyl ring

Uses

commonly used in organic synthesis as a reagent for various chemical reactions

Reactivity

known for its ability to undergo nucleophilic substitution reactions

Applications

potential applications in pharmaceuticals and agrochemicals

Safety

must be handled with care as it may have hazardous effects if not properly managed

Upstream product

• 7575-57-7 allyl benzenesulfonate 
• 139-02-6 sodium phenoxide 
• 107-05-1 3-chloroprop-1-ene 
• 88-75-5 2-hydroxynitrobenzene 
• 91-23-6 2-Nitroanisole 
• 107-18-6 allyl alcohol 
• 824-38-4 potassium 2-nitrophenoxide 
• 106-95-6 allyl bromide 
• 1493-27-2 ortho-nitrofluorobenzene 
• 824-39-5 sodium o-nitrophenate 

Downstream Products

• 114544-47-7 cis-N-<<2-methyl-3-(3-methylphenyl)-5-<(2-nitrophenyloxy)methyl>methylisoxazolidin-3-yl>methyl>-1H-1,2,4-triazole 
• 75571-14-1 2-prop-1-en-oxynitrobenzene 
• 1027344-31-5 ethyl 2-(3'-chloro-5'-trifluoromethyl-pyridin-2'-yl)-2-(3''-allyloxy-4''-nitrophenyl)propanoate 
• 122947-62-0 2-Allyloxy-4-dichloromethyl-1-nitro-benzene 
• 60333-71-3 Triethoxy-(3-o-nitrophenoxypropyl)-silan 
• 21407-49-8 2-nitrophenyl glycidyl ether 
• 132396-52-2 <2-(Allyloxy)phenyl>hydrazine 
• 98-54-4 para-tert-butylphenol 
• 3079-53-6 1-nitro-2-propoxybenzene 
• 1227833-96-6 (R)-3-(2-nitrophenoxy)propane-1,2-diol 
• 785817-21-2 (S)-3-(2-nitrophenoxy)propane-1,2-diol 
• 113002-45-2 (E)-3-(2,3-dihydrobenzofuran-3-yl)-1-phenylpropene 
• 25125-40-0 1-(2-(allyloxy)phenyl)-2-(tetrafluoro-λ⁵-boraneyl)diazene 
• 1236063-57-2 1-(2-bromoallyloxy)-2-nitrobenzene 

Relevant articles and documents

Palladium-catalyzed anti-Markovnikov oxidative acetalization of activated olefins with iron(iii) sulphate as the reoxidant

This paper discloses the efficient palladium-catalyzed anti-Markovnikov oxidative acetalization of activated terminal olefins with iron(iii) sulfate as the reoxidant. This methodology requires mild reaction conditions and shows high regioselectivity toward anti-Markovnikov products and compatibility with a wide range of functional groups. Iron(iii) sulphate was the sole reoxidant used in this method. Various olefins like vinylarenes, aryl-allylethers, aryl or benzyl acrylates and homoallylic alcohols all reacted well providing anti-Markovnikov acetals, some of which represent orthogonally functionalized 1,3- and 1,4-dioxygenated compounds.

An efficient approach to 3-thioether-functionalized 2,3-dihydrobenzofurans via a metal-free intramolecular radical cyclization/thiolation cascade reaction

A diverse series of 3-thioether-functionalized 2,3-dihydrobenzofurans were prepared by an intramolecular radical cyclization/thiolation cascade reaction of alkenyl-tethered arenediazonium salts with thiophenols under transition-metal-free conditions. The

Boron-Promoted Ether Interchange Reaction: Synthesis of Alkyl Nitroaromatic Ethers from Methoxynitroarenes

The first protocol for boron-promoted ether interchange reaction of methoxynitroarenes was described. A series of methoxynitroarenes and alcohols, including primary, secondary, as well as tertiary alcohols were reacted smoothly in moderate to good yields under the optimized reaction conditions. This protocol constitutes an operationally simple and scalable strategy for the synthesis of alkyl nitroaromatic ethers. Moreover, the new reactivity of boron reagents was discovered.