2-(phenylethyn-1-yl)-1,3-bis(trimethysilyl)-2-dimethyl(ethyl)amine-1,3,2-diazaalumina-[3]ferrocenophane

Base Information

• Chemical Name: 2-(phenylethyn-1-yl)-1,3-bis(trimethysilyl)-2-dimethyl(ethyl)amine-1,3,2-diazaalumina-[3]ferrocenophane
• CAS No.: 1085427-91-3
• Molecular Formula: C₂₈H₄₂AlFeN₃Si₂
• Molecular Weight: 559.661
• Mol file: 1085427-91-3.mol

Synonyms:

Chemical Property of 2-(phenylethyn-1-yl)-1,3-bis(trimethysilyl)-2-dimethyl(ethyl)amine-1,3,2-diazaalumina-[3]ferrocenophane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(phenylethyn-1-yl)-1,3-bis(trimethysilyl)-2-dimethyl(ethyl)amine-1,3,2-diazaalumina-[3]ferrocenophane

There total 1 articles about 2-(phenylethyn-1-yl)-1,3-bis(trimethysilyl)-2-dimethyl(ethyl)amine-1,3,2-diazaalumina-[3]ferrocenophane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-bis(trimethylsilyl)-2-dimethyl(ethyl)amine-2-hydro-1,3,2-diazaalumina-[3]ferrocenophane (952208-09-2) + phenylacetylene (536-74-3) → 1,1′-bis(trimethylsilylamino)ferrocene (337456-24-3) + 2-(phenylethyn-1-yl)-1,3-bis(trimethysilyl)-2-dimethyl(ethyl)amine-1,3,2-diazaalumina-[3]ferrocenophane (1085427-91-3)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: H2, 1,3,5-triphenylbenzene; under inert atm., 2 equiv. of the alkyne was added to the Fe-compd. at 0°C, warming to room temp., stirring for 20 h; volatiles were removed in vac., residue was dissolved in CD2Cl2, soln. was filtered; other olefinic products were also formed, components of themixt. were not sepd.;

DOI:10.1515/znb-2007-1005

Reference yield:

pyridine (110-86-1) + 2-(phenylethyn-1-yl)-1,3-bis(trimethysilyl)-2-dimethyl(ethyl)amine-1,3,2-diazaalumina-[3]ferrocenophane (1085427-91-3) → 1,1′-bis(trimethylsilylamino)ferrocene (337456-24-3) + 2-(phenylethyn-1-yl)-1,3-bis(trimethysilyl)-2-pyridine-1,3,2-diazaalumina-[3]ferrocenophane (1085428-01-8)

Guidance literature:

In ⁽²⁾H₈-toluene; byproducts: EtNMe2; under inert atm., 1 equiv. of pyridine was added to the soln. of Fe-compd. at 0 °C, stirring for 1 h; centrifugation, a mixt. was formed and not sepd.;

DOI:10.1515/znb-2007-1005

upstream raw materials:

1,3-bis(trimethylsilyl)-2-dimethyl(ethyl)amine-2-hydro-1,3,2-diazaalumina-[3]ferrocenophane

phenylacetylene

Downstream raw materials:

1,1′-bis(trimethylsilylamino)ferrocene

2-(phenylethyn-1-yl)-1,3-bis(trimethysilyl)-2-pyridine-1,3,2-diazaalumina-[3]ferrocenophane