Silane, methylidynetris[dimethylphenyl-

Base Information

• Chemical Name: Silane, methylidynetris[dimethylphenyl-
• CAS No.: 27628-30-4
• Molecular Formula: C25H34Si3
• Molecular Weight: 418.801
• DSSTox Substance ID: DTXSID70452830
• Nikkaji Number: J1.267.349C
• Wikidata: Q82273678
• Mol file: 27628-30-4.mol

Synonyms:Silane, methylidynetris[dimethylphenyl-;27628-30-4;tris(dimethylphenylsilyl)methane;Tris(phenyldimethylsilyl)methane;DTXSID70452830

Chemical Property of Silane, methylidynetris[dimethylphenyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 418.19683069
• Heavy Atom Count: 28
• Complexity: 407

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C1=CC=CC=C1)C([Si](C)(C)C2=CC=CC=C2)[Si](C)(C)C3=CC=CC=C3

Technology Process of Silane, methylidynetris[dimethylphenyl-

There total 8 articles about Silane, methylidynetris[dimethylphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

chloro(dimethyl)(tris(dimethylphenylsilyl)methyl)stannane (113629-70-2) + methyllithium (917-54-4) → tris(phenyldimethylsilyl)methane (27628-30-4)

Guidance literature:

In tetrahydrofuran; diethyl ether; solution of MeLi (30 mmol) in Et2O was added to tin compound (0.83 mmol) in THF; stirring 0.5 h at room temperature;; excess of MeLi was destroyed by careful addition of MeOH inTHF; solvent was evaporated; extraction (CH2Cl2) yield the product;;

DOI:10.1016/0022-328X(88)89008-9

Reference yield: 80.0%

carbon disulfide (75-15-0,12122-00-8) + tris(dimethylphenylsilyl)methyllithium (63811-62-1) + methyloxirane (75-56-9,16033-71-9) → 5-methyl-1,3-oxathiolane-2-thione (21033-18-1) + tris(phenyldimethylsilyl)methane (27628-30-4)

Guidance literature:

In tetrahydrofuran; at 0 ℃; for 0.333333h; Inert atmosphere;

DOI:10.1080/17415993.2013.879307

Reference yield: 71.0%

Bromoform (75-25-2) + phenyldimethylsilyl chloride (768-33-2) → tris(phenyldimethylsilyl)methane (27628-30-4)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃;

DOI:10.1016/0022-328X(93)83340-2

upstream raw materials:

tris(dimethylphenylsilyl)methyllithium

(chloro)(methyl)silane

tetrachloromethane

phenyldimethylsilyl chloride

Downstream raw materials:

tris(dimethylphenylsilyl)methyllithium

((CH₃)2C₆H₅Si)3CNa

1,1,3,3-tetramethyl-1,3-diphenyldisiloxane

ethene-1,1-diylbis(dimethyl(phenyl)silane)