5,6-Dihydrophenanthridine

Base Information

• Chemical Name: 5,6-Dihydrophenanthridine
• CAS No.: 27799-79-7
• Molecular Formula: C13H11N
• Molecular Weight: 181.237
• Hs Code.: 2933990090
• Mol file: 27799-79-7.mol

Synonyms:5,6-Dihydro-phenanthridin;Phenanthridine,5,6-dihydro;9,10-Dihydro-9-aza-phenanthren;5,6-dihydro-phenanthridine;9,10-dihydrophenanthridine;Dihydrophenanthridine;

Chemical Property of 5,6-Dihydrophenanthridine

Chemical Property:

• Melting Point: 125 °C
• Boiling Point: 370.7±12.0 °C(Predicted)
• PKA: 3.52±0.20(Predicted)
• PSA: 12.03000
• Density: 1.117±0.06 g/cm3(Predicted)
• LogP: 3.41710

Purity/Quality:

98%min ^*data from raw suppliers

5,6-DIHYDRO-PHENANTHRIDINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5,6-Dihydrophenanthridine

There total 5 articles about 5,6-Dihydrophenanthridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

N-allyl-2-(2-furyl)aniline (1359768-78-7) → phenanthridine (229-87-8) + 5,6-dihydrophenanthridine (27799-79-7)

Guidance literature:

With hydrogenchloride; In water; acetonitrile; at 170 ℃; for 5h; Inert atmosphere; Microwave irradiation;

DOI:10.1021/jo3027033

Reference yield:

6(5H)-phenanthridinone (1015-89-0) → phenanthridine (229-87-8) + 5,6-dihydrophenanthridine (27799-79-7)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 4h; Reflux;

Reference yield:

phenanthridine N-oxide (14548-01-7) → phenanthridine (229-87-8) + 5,6-dihydrophenanthridine (27799-79-7)

Guidance literature:

With tris(bipyridine)ruthenium(II) dichloride hexahydrate; hydrazine hydrate; In dimethyl sulfoxide; at 20 ℃; for 12h; Overall yield = 64 %; Inert atmosphere; Irradiation;

DOI:10.1021/acs.orglett.8b03446

upstream raw materials:

C₁₈H₂₀BrNO₂

N-[4-methylphenyl]sulfonyl-5,6-dihydrophenanthridine

N-allyl-2-(2-furyl)aniline

phenanthridine N-oxide

Downstream raw materials:

N-benzoyl-(6H)phenanthridine

phenanthridine

1-(6H-Phenanthridin-5-yl)-4-phenyl-butan-1-one

1-(6H-Phenanthridin-5-yl)-2-phenyl-ethanone