Spiro[2.4]hepta-4,6-diene, 1-phenyl-, (1R)-

Base Information

Chemical Name:Spiro[2.4]hepta-4,6-diene, 1-phenyl-, (1R)-
CAS No.:278169-73-6
Molecular Formula:C13H12
Molecular Weight:168.238
Hs Code.:
DSSTox Substance ID:DTXSID30463280
Nikkaji Number:J2.316.252K

Synonyms:Spiro[2.4]hepta-4,6-diene, 1-phenyl-, (1R)-;278169-73-6;DTXSID30463280

Suppliers and Price of Spiro[2.4]hepta-4,6-diene, 1-phenyl-, (1R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 0 raw suppliers

Chemical Property of Spiro[2.4]hepta-4,6-diene, 1-phenyl-, (1R)-

Chemical Property:

XLogP3:3.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:168.093900383
Heavy Atom Count:13
Complexity:241

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C(C12C=CC=C2)C3=CC=CC=C3
Isomeric SMILES:C1[C@@H](C12C=CC=C2)C3=CC=CC=C3

Technology Process of Spiro[2.4]hepta-4,6-diene, 1-phenyl-, (1R)-

There total 2 articles about Spiro[2.4]hepta-4,6-diene, 1-phenyl-, (1R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 278169-72-5
(R)-phenyl-1,2-bis(methanesulfonyloxy)ethane

: 278169-73-6
(R)-1-phenyl-spiro[2.4]hepta-4,6-diene

Guidance literature:: With sodium amide; In tetrahydrofuran; at 20 ℃;
DOI:10.1002/ejic.200300934

Reference yield:

: 16355-00-3
(R)-1-phenyl-1,2-ethanediol

: 278169-73-6
(R)-1-phenyl-spiro[2.4]hepta-4,6-diene

Guidance literature:: Multi-step reaction with 2 steps

1: Et₃N / CH₂Cl₂

2: NaNH₂ / tetrahydrofuran

With sodium amide; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.jorganchem.2005.10.044

Reference yield: 88.0%

: 29949-64-2
di(o-tolyl)phosphine

: 278169-73-6
(R)-1-phenyl-spiro[2.4]hepta-4,6-diene

: 514196-66-8
(S)-LiC₅H₄CH₂CHPhP(o-Tol)2

Guidance literature:: di(o-tolyl)phosphine; With n-butyllithium; In tetrahydrofuran; hexane; at -60 - 20 ℃;

(R)-1-phenyl-spiro[2.4]hepta-4,6-diene; at 20 ℃;
DOI:10.1016/S0022-328X(02)01732-1