[(κ(P),κ(C),κ(P)-2,6-(Ph2PO)2C6H3)NiBr]

Base Information

• Chemical Name: [(κ(P),κ(C),κ(P)-2,6-(Ph2PO)2C6H3)NiBr]
• CAS No.: 1303996-71-5
• Molecular Formula: C₃₀H₂₃BrNiO₂P₂
• Molecular Weight: 616.053
• Mol file: 1303996-71-5.mol

Synonyms:

Chemical Property of [(κ(P),κ(C),κ(P)-2,6-(Ph2PO)2C6H3)NiBr]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(κ(P),κ(C),κ(P)-2,6-(Ph2PO)2C6H3)NiBr]

There total 8 articles about [(κ(P),κ(C),κ(P)-2,6-(Ph2PO)2C6H3)NiBr] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

[(2,6-(Ph2PO)2C6H3)Ni(SC6H5)] (1254730-51-2) + benzyl bromide (100-39-0) → [(κ(P),κ(C),κ(P)-2,6-(Ph2PO)2C6H3)NiBr] (1303996-71-5)

Guidance literature:

In toluene; byproducts: PhSCH2Ph; (Ar); std. Schlenk technique; mixt. of Ni complex and C6H5CH2Br in toluene was stirred at 80°C for 16 h; cooled to room temp.; filtered through Celite; evapd. (vac.); recrystd. (CH2Cl2/hexane, 1/2); elem. anal.;

DOI:10.1039/c2dt30407d

Reference yield: 88.0%

NiBr2(CH3CN)2 (14515-44-7) + 1,3-bis(diphenylphosphinito)benzene (279214-81-2) → [(2,6-(Ph2PO)2C6H3-κ3C,P,P')NiBr] (1303996-71-5)

Guidance literature:

In toluene; (N2); addn. of nickel compd. and triethylamine to stirred soln. of diphosphine deriv. in toluene, stirring at 25°C for 12 h; evapn., extn. (anhyd. CHCl3), filtration through silica gel, evapn. in vac., elem. anal.;

DOI:10.1039/c1dt10381d

Reference yield:

trityl chloride (76-83-5) → [(κ(P),κ(C),κ(P)-2,6-(Ph2PO)2C6H3)NiBr] (1303996-71-5)

Guidance literature:

Multi-step reaction with 3 steps

1: ⁽²⁾H₈-toluene

2: NaH / tetrahydrofuran

3: ⁽²⁾H₈-toluene

With NaH; In tetrahydrofuran; ⁽²⁾H₈-toluene;

DOI:10.1039/c2dt30407d

upstream raw materials:

NiBr₂(CH₃CN)₂

1,3-bis(diphenylphosphinito)benzene

[(2,6-(Ph₂PO)2C₆H₃)Ni(SC₆H₅)]

benzyl bromide

Downstream raw materials:

[(κ(P),κ(C),κ(P)-2,6-(Ph2PO)2C6H3)Ni(O3SCF3)]

[(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(acetate)]

[(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(CN)]

[(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(nitrate)]