(E)-1-(Phenylsulfonyl)-1-propene

Base Information

• Chemical Name: (E)-1-(Phenylsulfonyl)-1-propene
• CAS No.: 28691-72-7
• Molecular Formula: C9H10O2S
• Molecular Weight: 182.243
• Hs Code.: 2904100000
• Mol file: 28691-72-7.mol

Synonyms:(E)-1-benzenesulfonyl-propene;phenyl (E)-prop-1-en-1-yl sulfone;(E)-1-(phenylsulfonyl)-1-propene;phenyl trans-1-propenyl sulfone;(E)-1-phenylsulfonyl-2-propene;1-[(E)-prop-1-enylsulfonyl]benzene;

Chemical Property of (E)-1-(Phenylsulfonyl)-1-propene

Chemical Property:

• PSA: 42.52000
• LogP: 3.07470

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (E)-1-(Phenylsulfonyl)-1-propene

There total 31 articles about (E)-1-(Phenylsulfonyl)-1-propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

sodium benzenesulfonate (873-55-2) + allyl bromide (106-95-6) → (allylsulfonyl)benzene (16212-05-8) + phenyl ((Z)-prop-1-en-1-yl) sulfone (40410-87-5) + (E)-1-propenyl phenyl sulfone (28691-72-7)

Guidance literature:

With aluminum oxide; for 2h; Irradiation;

Reference yield: 95.0%

(allylsulfonyl)benzene (16212-05-8) → (E)-1-propenyl phenyl sulfone (28691-72-7)

Guidance literature:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); In benzene; for 6h; Heating;

DOI:10.1016/S0022-328X(02)02111-3

Reference yield: 92.0%

1-(phenylsulfonyl)-2-propanol (68276-72-2) → (E)-1-propenyl phenyl sulfone (28691-72-7)

Guidance literature:

With methanesulfonyl chloride; triethylamine; In dichloromethane; at 20 ℃; for 6h;

DOI:10.1080/00397910008087440

upstream raw materials:

phenyl (E)-propenyl sulphide

(allylsulfonyl)benzene

Allyl acetate

sodium benzenesulfonate

Downstream raw materials:

(3SR,4SR,5RS)-2,3-diphenyl-4-(phenylsulfonyl)-5-methylisoxazolidine

E-1-(phenylsulfonyl)-1-(trimethylsilyl)-prop-1-ene

(3S,4S,5R)-4-Benzenesulfonyl-5-methyl-3-(4-nitro-phenyl)-2-phenyl-isoxazolidine

2-(adamant-1-yl)-1-phenylsulphonyl-1-(pyridine-2-thiyl) propane

Refernces

• 1、 Julia, M.,Lauron, H.,Verpeaux, J. N.,Jeannin, Y.,Bois, C.. "Synthesis, structure, and stability of cyclopentadienyl(triphenylphosphine)(α-benzenesulfonylalkyl)nickel complexes". . p. C11 - C16. Retrieved 1988.
• 2、 Chang, Meng-Yang,Wu, Yan-Shin,Hsiao, Yu-Ting. "Gram-scale synthesis of β-sulfonyl styrenes". . p. 4651 - 4658. Retrieved 2019/02/01.
• 3、 Mauleon, Pablo,Alonso, Ines,Rivero, Marta Rodriguez,Carretero, Juan C.. "Enantioselective synthesis of chiral sulfones by Rh-catalyzed asymmetric addition of boronic acids to α,β-unsaturated 2-pyridyl sulfones". . p. 9924 - 9935. Retrieved 2008/03/28.