112752-02-0

• 

• Basic information

  1. Product Name: 4 4'-BIPHENOL BIS(TRIFLUOROMETHANE-
  2. Synonyms: 4 4'-BIPHENOL BIS(TRIFLUOROMETHANE-;4,4`-Biphenol bis(trifluoroMethanesulfonate),98%
  3. CAS NO:112752-02-0
  4. Molecular Formula: C14H8F6O6S2
  5. Molecular Weight: 450.3301392
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 112752-02-0.mol
  9. Article Data: 5

• Chemical Properties

  1. Melting Point: 64-66 °C(lit.)
  2. Boiling Point: 455.9±45.0 °C(Predicted)
  3. Flash Point: N/A
  4. Appearance: /
  5. Density: 1.622±0.06 g/cm3(Predicted)
  6. Refractive Index: N/A
  7. Storage Temp.: N/A
  8. Solubility: N/A
  9. CAS DataBase Reference: 4 4'-BIPHENOL BIS(TRIFLUOROMETHANE-(CAS DataBase Reference)
  10. NIST Chemistry Reference: 4 4'-BIPHENOL BIS(TRIFLUOROMETHANE-(112752-02-0)
  11. EPA Substance Registry System: 4 4'-BIPHENOL BIS(TRIFLUOROMETHANE-(112752-02-0)

• Safety Data

  1. Hazard Codes: Xi
  2. Statements: 36/37/38
  3. Safety Statements: 26
  4. WGK Germany: 3
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 112752-02-0(Hazardous Substances Data)

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• 4,4-BIPHENOL BIS(TRIFLUOROMETHANE-SULFON ATE)

  Cas No: 112752-02-0

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• 4,4'-BIPHENOL BIS(TRIFLUOROMETHANE-

  Cas No: 112752-02-0

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112752-02-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 112752-02-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,2,7,5 and 2 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 112752-02:
(8*1)+(7*1)+(6*2)+(5*7)+(4*5)+(3*2)+(2*0)+(1*2)=90
90 % 10 = 0
So 112752-02-0 is a valid CAS Registry Number.

112752-02-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name	[4-[4-(trifluoromethylsulfonyloxy)phenyl]phenyl] trifluoromethanesulfonate

1.2 Other means of identification

Product number	-
Other names	4,4 inverted exclamation marka-Biphenol bis(trifluoromethanesulfonate)

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:112752-02-0 SDS

112752-02-0Upstream product

• 66107-30-0 4-bromophenyl trifluoromethanesulfonate 
• 105-13-5 4-Methoxybenzyl alcohol 
• 109586-39-2 4-iodophenyl trifluoromethanesulfonate 
• 2969-81-5 Ethyl 4-bromobutyrate 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 92-88-6 4,4'-Dihydroxybiphenyl 

112752-02-0Downstream Products

• 92-52-4 biphenyl 
• 6120-99-6 4,4'-dideuterio-biphenyl 

112752-02-0Relevant articles and documents

Nickel catalyzed deoxygenative cross-coupling of benzyl alcohols with aryl-bromides

Kumar Chenniappan, Vinoth,Peck, Devin,Rahaim, Ronald

supporting information, (2020/03/03)

A nickel-catalyzed cross-electrophile coupling of benzyl alcohols with aromatic bromides has been developed. This deoxygenative cross-coupling occurs under mild reaction conditions at ambient temperature affording diarylmethanes, or 1,3-diarylpropenes from benzyl allyl alcohols. The system demonstrated good chemoselectivity tolerating an assortment of reactive functional groups.

Homocoupling of iodoarenes and bromoalkanes using photoredox gold catalysis: A light enabled Au(III) reductive elimination

Tran, Huy,McCallum, Terry,Morin, Mathieu,Barriault, Louis

supporting information, p. 4308 - 4311 (2016/09/09)

The formation of homocoupled alkane byproducts have been identified in the reduction of bromoalkanes via photoredox gold catalysis with dimeric Au(I) complexes. This prompted further investigation into the mechanism of formation of these byproducts and the diversity of C-X bonds amenable to this transformation. Examples were found when considering bromoalkanes while a wide variety of iodoarenes underwent this process in good to excellent yields. The light enabled homocoupling of iodoarenes made possible by photoredox gold catalysis is reported.

Palladium Catalysed Alkoxycarbonylation of Phenols to Benzoate Esters

Dolle, Roland E.,Schmidt, Stanley J.,Kruse, Lawrence I.

, p. 904 - 905 (2007/10/02)

The methoxycarbonylation of aryl trifluoromethanesulphonates with CO and aliphatic alcohols is catalysed by Pd(OAc)2-1,3-bis(diphenylphosphino)propane in high yield at 70 deg C and ambient CO pressure.

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